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Data Storage Earth Science

Could Granite Solve the Hard Problem of Nuclear Waste Storage? (theguardian.com) 152

An anonymous reader quotes a report from The Guardian: A new study published in Scientific Reports reveals that crystalline rocks, such as granite, have a natural self-sealing mechanism, capable of keeping fluids locked away for millions of years. Careful analysis of the chemistry and structure of granites from Japan and the UK revealed that when fluid did enter the rock (via fractures), it travelled a few centimeters at most. The scientists believe that calcium in the rock reacted with carbonate in the fluid to create tiny crystals of calcite that plugged all the gaps and prevented further flow. "This amount of calcite would never be expected in a granite, and the distribution of it indicates it almost certainly formed from small quantities of fluid trying to move through the rock," says Roy Wogelius from the University of Manchester. Greater understanding is needed before we finalize our radioactive waste disposal strategies, but this is a promising step forward.
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Could Granite Solve the Hard Problem of Nuclear Waste Storage?

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  • We've been taking nuclear power for granite.

  • by gurps_npc ( 621217 ) on Wednesday June 03, 2020 @10:33PM (#60143352) Homepage

    Is to store it in the basement of the US Capitol building until Congress chooses a better location.

    • Re: (Score:2, Informative)

      by Gravis Zero ( 934156 )

      Congress already chose a location: Yucca Mountain in Nevada. The problem is the locals decided they were going to refuse to allow storage (after years of building the facility).

      Bottom line: humans are selfish and stupid.

    • by GuB-42 ( 2483988 )

      Properly stored, I wouldn't mind having nuclear waste in my basement.
      Spent fuel pools for instance would be perfectly safe to swim in it wasn't for the risk of getting shot ( https://what-if.xkcd.com/29/ [xkcd.com] )

      The main risk with radioactive materials is if it enters your body, for example if you drink contaminated water or breathe radioactive dust. At a distance, only gamma and x-rays are a problem and they can be shielded with lead bricks down to levels not exceeding background. Keep in mind that high level was

  • Why? (Score:3, Informative)

    by wagnerer ( 53943 ) on Wednesday June 03, 2020 @10:49PM (#60143386)
    Permanent disposal is solved. The deep salt mines in TX and NM will hold it for billions of years. This might be useful for countries without that particular geologic formation. The only reason you'd need millions of years of storage is 1) you assume cancer won't be cured in millions of years and 2) You don't reprocess. If cancer is cured than low level radiation leakages don't have a health hazard. If you reprocess, the waste that remains has a half life of around 30 years. After only 300 years you have less than 1% of it remaining. 600 years 1% of 1% remaining. I think the best way to get 'rid' of the short lived stuff is dry it out and package it into RTGs and dump the power into the grid. Every century or so re-concentrate it since so much would have decayed away.
    • Re:Why? (Score:5, Informative)

      by blindseer ( 891256 ) <blindseer@earthli[ ]net ['nk.' in gap]> on Thursday June 04, 2020 @12:18AM (#60143578)

      I think the best way to get 'rid' of the short lived stuff is dry it out and package it into RTGs and dump the power into the grid.

      It would be a better idea to use them off the grid.

      RTGs were used to power very remote lighthouses and navigation beacons before GPS was a thing. RTGs are also how we sent people to the moon and probes to Mars and beyond. NASA is desperate for material for making RTGs but the legal and logistical problems of reprocessing spent nuclear fuel makes this impractical. What NASA ended up doing, as I recall, was build their own nuclear reactor to make Pu-238.

      • by pjt33 ( 739471 )

        NASA currently sources its plutonium from Oak Ridge National Laboratory, but I don't know how long that's been the case.

      • by AmiMoJo ( 196126 )

        It's not a NASA reactor. They are paying Oak Ridge to make it for them. Goal is for 1.5kg/year by 2025, at a cost of about $20M/year.

        https://www.businessinsider.co... [businessinsider.com]

      • by MobyDisk ( 75490 )

        I don't think it is possible to use radioactive waste or spent nuclear fuel as a source for an RTG, for the same reasons it is not useful in the nuclear plant. To be clear, there are two things we are talking about here: "radioactive waste" and "spent nuclear fuel." The "radioactive waste" is mostly junk that is not radioactive enough to produce heat for an RTG and not compatible with nuclear reactors. If it was, we would just put it back into the reactor. The "spent nuclear fuel" still has 96% of the u

      • by hey! ( 33014 )

        That's an interesting idea, but not without its drawbacks and I don't think it really solves the waste problem because the really good stuff (Pu-238 and stuff that can be transformed into it) is a small fraction of the waste.

        The most abundant isotopes are Ce-137 and Sr-90. These could be used in RTGs, but they're not as handy for RTG design as Pu-238 for that purpose because they emit beta (and for Ce-137's daughter products, gamma) rays. Pu-238 RTGs are not only simpler, they're smaller and lighter for th

    • by AmiMoJo ( 196126 )

      If cancer is cured than low level radiation leakages don't have a health hazard.

      Depends what the treatment is like and if it is available for all plants and animals that are affected too. Seems like a lot of effort compared to just properly storing it.

    • If you reprocess, the waste that remains has a half life of around 30 years. After only 300 years you have less than 1% of it remaining. 600 years 1% of 1% remaining.

      I think your math is off here. 300 years with a half life of 30 years is 10 half lifes. Wouldn't this be 1/(2^10), or around 0.1%?

  • Comment removed (Score:5, Interesting)

    by account_deleted ( 4530225 ) on Wednesday June 03, 2020 @10:51PM (#60143390)
    Comment removed based on user account deletion
    • I keep hearing this, is there any reason it isn't being done other than new plants in general aren't being built?

      • Re:Don't (Score:5, Informative)

        by jandrese ( 485 ) <kensama@vt.edu> on Thursday June 04, 2020 @12:43AM (#60143608) Homepage Journal
        Breeder reactors are very expensive and nuclear fuel is cheap.

        Nuclear waste is 100% a political problem, not a scientific one. The total amount of waste generated by all of the US Nuclear reactors ever fits in about 16 Olympic size swimming pools. Storing it safely effectively forever is not difficult technically, but is basically impossible politically. If you think about it these reactors have been running for several decades without a waste solution and somehow have not run out of space on-site to store it, the total volume can't be too large. It's not like the fly ash from coal that would completely bury the average plant after only a few years if it wasn't trucked away constantly.

        As for why new plants aren't being built, that's mostly political too. It's a shame too because pushback on nuclear has ironically increased the amount of radiation in the atmosphere. Coal plants release more radioactive material in the air every year than was released in the Chernobyl disaster in addition to releasing planet destroying levels of greenhouse gasses.
        • by pjt33 ( 739471 )

          The total amount of waste generated by all of the US Nuclear reactors ever fits in about 16 Olympic size swimming pools.

          I think that statement's missing a qualifier. It's probably right for "high-level" waste, but it's important to remember that there's also low-level waste, some produced on a regular basis during operation of a plant but also part of the plant itself when the time comes to mothball it. I suspect it's less of a political hot potato because no-one ever thinks about it: if they did, knee-jerk

          • by pakar ( 813627 )

            If they made people think they would never again be able to scream "Think of the children!".

        • by AmiMoJo ( 196126 )

          It's not a political problem, it's an economic one. The political issues would have been solved if nuclear had delivered on the promise of extremely cheap energy, but it turned out to be really expensive energy so the will to deal with the waste problem went away.

        • My understanding is that they are not profitable. The idea would be to use the radioactive waste to generate electricity to sell to a grid. However if it costs more to use this type of reactor than electricity sales, then private companies would never build one and few government would operate one other than as a waste removal cost. Adding to this is that it’s is far cheaper to use wind or solar. Maybe in the future, there may be a greater need and will to use them.

        • Re:Don't (Score:5, Informative)

          by MobyDisk ( 75490 ) on Thursday June 04, 2020 @09:48AM (#60144636) Homepage

          The total amount of waste generated by all of the US Nuclear reactors ever fits in about 16 Olympic size swimming pools.

          I keep hearing this quote so I wanted to fact check it.

          Facts:
          US GAO says: 90,000 metric tons of high-level nuclear waste total [gao.gov]
          Spent nuclear fuel is 96% uranium [wikipedia.org].
          Ergo:
          that is ~4700 cubic meters, or ~1.9 Olympic swimming pools. [wolframalpha.com] Close enough!

          Next steps:
          What about the low-level nuclear waste?
          US generates 40,000 cubic meters per year [wikipedia.org]. So is this stuff the actual problem [wikipedia.org]?

      • Re:Don't (Score:4, Interesting)

        by blindseer ( 891256 ) <blindseer@earthli[ ]net ['nk.' in gap]> on Thursday June 04, 2020 @12:46AM (#60143612)

        I keep hearing this, is there any reason it isn't being done other than new plants in general aren't being built?

        That's pretty much it, but not the whole story.

        Because no new nuclear power plants are being built there's no market for reprocessing fuel, there's no money in it. The kind of reactors needed to consume this kind of fuel is not the same kind that dominate nuclear power today, the light water reactor. There are heavy water reactors that can consume "spent" fuel from light water reactors but many of them have a feature that's known as "positive void coefficient". This feature is shared with the old RBMK reactors at Chernobyl. This is, as I recall, what has made it difficult to build a new heavy water reactor. Which is perhaps understandable since this positive void coefficient was the "feature" that lead to the destruction of one of those RBMK reactors. I don't know if there is a way to remove this "feature" without also destroying the ability of the reactor to consume what is now considered "spent" fuel.

        There's other reactor designs that claim to be able to consume what is currently considered "spent" fuel. Since many nations stopped building new reactors there's no incentive to develop the technology. Any reactor built in the last 30 years or so are considered "third generation", which are merely a cheaper and safer evolution of the second generation reactors like the RBMK (Chernobyl), BWR (like at Fukushima and in my backyard), or PWR (Three Mile Island). The kind of reactors that burn "spent" fuel are either fourth generation, which are currently in development, or experimental first generation reactors that would be considered far too primitive to be constructed today.

        As currently operational nuclear power reactors reach the end of their operational life, which will come soon, there will be a renewed interest in building new reactors to replace them. The first of them will likely be third generation reactors much like those we've seen build since about 1990. Then will come the fourth generation reactors that can consume this "spent" fuel we've piled up over decades.

        • by AmiMoJo ( 196126 )

          That's not the whole story. Fact is that every reactor capable of consuming spent fuel has been an expensive fiasco. None of them worked properly, all had expensive problems and were eventually abandoned. Maybe someone will figure it out eventually but the desire to throw billions of dollars at them is dwindling fast.

          4th gen has been the promised saviour for decades but no one has even successfully demonstrated a commercial scale one, and the small scale demos have not exactly gone well.

          If you disagree then

          • That's not the whole story.

            Of course not. To tell the whole story would take volumes.

            Fact is that every reactor capable of consuming spent fuel has been an expensive fiasco. None of them worked properly, all had expensive problems and were eventually abandoned. Maybe someone will figure it out eventually but the desire to throw billions of dollars at them is dwindling fast.

            No, the desire is increasing rapidly. In the last 40+ years we've built only a handful of new nuclear reactors, and closed perhaps a dozen. The ones that remain will reach end of life soon. When they do reach end of life something will have to replace them, and given our reliance on so many nuclear reactors it will be nearly impossible to replace them with any other than new nuclear reactors. Such new construction opens an opportunity to build n

        • Comment removed based on user account deletion
          • GE/Hitachi claim that the spent fuel reactors cannot melt down.

            Most proposed Gen V reactor types can't melt down despite what fuel you give them.

      • Comment removed (Score:4, Informative)

        by account_deleted ( 4530225 ) on Thursday June 04, 2020 @12:53AM (#60143632)
        Comment removed based on user account deletion
      • by Luckyo ( 1726890 )

        Proliferation. Same plants can be used to enrich weapons grade material. Controls you'd need to apply to personnel and processes to "avoid any lost/misplaced material, ever" would need to be extreme.

        • Re:Don't (Score:5, Interesting)

          by blindseer ( 891256 ) <blindseer@earthli[ ]net ['nk.' in gap]> on Thursday June 04, 2020 @07:23AM (#60144232)

          Proliferation. Same plants can be used to enrich weapons grade material.

          Isn't that like saying we could be using gasoline to make napalm, or diesel fuel to make ANFO?

          What makes the processing of spent fuel from civilian power plants different than the processing of materials from weapons producing reactors is the mix of isotopes involved in the source material. To get weapon grade material means running the reactors in a way that is very much non-optimal for producing power. The process is similar but the source materials are very different.

          Controls you'd need to apply to personnel and processes to "avoid any lost/misplaced material, ever" would need to be extreme.

          The "controls" needed would be to make sure that no enrichment happens. The uranium and plutonium that comes from spent nuclear fuel is sufficiently tainted with isotopes to make it worthless for bombs. Since enrichment of spent fuel is only necessary to make weapons, not to make fuel, then it should be quite apparent on the intent if someone is operating an enrichment facility fed with spent fuel.

          What keeps uranium from fuel worthless is the production of U-236, which is nearly nonexistent in natural uranium but builds up in the uranium isotope mix as fuel is reprocessed. This can only be removed with considerable effort by enrichment, so difficult that it would be far easier to use naturally occurring uranium instead. Natural uranium is available out of the dirt nearly everywhere on Earth, and will not be guarded by people armed with machine guns.

          What keeps plutonium from spent fuel worthless is the buildup of Pu-240, something that is also difficult to remove even with access to enrichment facilities. It would be easier to build a new reactor to bombard uranium with neutrons than to try to extract it from spent fuel. Just build the reactor where there's no people with machine guns guarding it to stop you.

          There is no need for "extreme" measures to protect the fuel. The fuel protects itself against weapon proliferation with the presence of isotopes that would destroy it's utility in any weapon. These isotopes will "steal" neutrons and make any weapon a dud. They will also bombard any person or electronics around them with enough gamma and neutron radiation to kill them over time. This radiation will also "scream" to any detectors giving away it's location if someone were to try to remove any quantity of significance.

          These weapon proliferation risks are overblown by ignorant fear mongers.

          • What keeps plutonium from spent fuel worthless is the buildup of Pu-240, something that is also difficult to remove even with access to enrichment facilities. It would be easier to build a new reactor to bombard uranium with neutrons than to try to extract it from spent fuel. Just build the reactor where there's no people with machine guns guarding it to stop you.

            There are many subtleties of nuclear chemistry that are lost on nearly everyone. A nuclear reactor that is not designed specifically for plutonium production makes for absurdly expensive plutonium. Using a normal reactor designed for production of electricity is so impractical as to be throwing money away. There are easier ways.

            The concern around the Iranian reactors was there were a specific one that could be altered to be good enough neutron source for practical plutonium production.
            That one reactor re

          • by Luckyo ( 1726890 )

            >Isn't that like saying we could be using gasoline to make napalm, or diesel fuel to make ANFO?

            Sure. But high explosive weapons do not command the same MAD value that nuclear weapons do. MAD triad is NBC only.

      • by MrKaos ( 858439 )

        I keep hearing this, is there any reason it isn't being done other than new plants in general aren't being built?

        Yes, the oil and coal industry lobbied to have the functioning prototype shutdown and destroyed. You can verify that in SEC. 628. of the U.S Energy Policy Act [congress.gov].

        • Yes, the oil and coal industry lobbied to have the functioning prototype shutdown and destroyed.

          Not sure what you're smoking but we have reprocessed uranium for many years. There's no need to blame the oil and coal industry when governments themselves are shit scared of the proliferation aspect of it. There's not much technical difference between a reactor that can use spent uranium as fuel and a reactor purpose built for the production of plutonium.

          The issue is 100% political and several such plants exist around the world.

          • Re:Don't (Score:5, Interesting)

            by MrKaos ( 858439 ) on Thursday June 04, 2020 @08:40AM (#60144430) Journal

            There's no need to blame the oil and coal industry when governments themselves are shit scared of the proliferation aspect of it. There's not much technical difference between a reactor that can use spent uranium as fuel and a reactor purpose built for the production of plutonium.

            The reactor they're talking about is the IFR prototype which was a *burner* reactor. It's waste product was fissile ash, so it was configured to be an *anti*-proliferation reactor.

            The oil and coal industry didn't want it developed because it produced hydrogen AND electricity. With the existing stocks of plutonium and DU it would have solved the waste problems and provided enough fuel for the next 5000 years without the need for mining whilst keeping existing vehicle fleets.

            I've pointed out before that there were good people working in the nuclear industry that *listened* to the concerns of the anti-nuclear folk and used it as the impetus to design a better kind of nuclear reactor that addresses their concerns. That's the problem with the discussion about nuclear power, it's become so polarised no one listens anymore. Just blah blah nuculaar.

            The issue is 100% political and several such plants exist around the world.

            Please point out operational reactors with burn-up rates approaching 20% of the fuel.

            The whole idea behind them was to export the design and make nuclear armament too expensive compared to the value of fuel and electricity. That's the America the world admired, but the oil and coal industry soon put a stop to that so their worldwide profits would be maintained.

            Now people exist in this fantasy that one day some special new reactor technology will be invented that solves all these problems, when the reality is that it was invented, tested and reactor experience was gained. Sure there were materials technology issues to solve, but it was a start.

            The funding I'm referring to is to completely *destroy* a technology that most nuclear advocates aren't even aware of so that it is never developed and can never be studied. No one else is going to lobby the government to repeal SEC 628. of the US Energy Act to save the technology taxpayers funded so I'd like to see how it's the greenies fault this time.

      • I keep hearing this, is there any reason it isn't being done other than new plants in general aren't being built?

        Yes, politics. Reprocessing of Uranium into fuel generates about 1% plutonium as a bi-product. There are several plants that do this and they are under a very careful and watchful eye as they then recycle plutonium in the MOX process, and that is one nasty process as well.

        That's fundamentally it. It's not the uranium that is the problem. No one wants to deal with the headache of managing the plutonium side product.

      • Cost. It’s like recycling in that for the most part it’s not profitable to recycle some materials like plastic which are cheaper to landfill. Some materials like aluminum are worth recycling. The idea of a breeder reactor is sound only if the true purpose is to remove the waste and not to generate any profits. So no private companies would ever build one.
    • by JackAxe ( 689361 )
      I recall watching a documentary on this, but I can't recall the name of the reactor type. The reactors being developed in the eighties would clean and reuse the fuel. Then by the time the fuel had been spent, it would only be dangerous for a few hundred years. I also recall a lady scientist working on this, so that 100% of all fuel could be reused.

      I'm pro nuclear power. I find it ironic that oil companies are behind much of the propaganda against nuclear power, which most people blindly parrot.
      • Why is it ironic that companies pushing one type of product would spread FUD about another, arguably better type of product pushed by their competitors?
      • The problem with all those designs has been that uranium supply didn't turn out to be the limiting factor. In fact fresh uranium is so cheap these days that often even conservative and simple approaches like MOX fuel turned out to be not all that advantageous.
  • What about slowly dripping it from a ship so it dilutes it into the ocean .. whats the math on that ? How much would it add to the background? Or remix and return it back to the mine? Can't be more long term radioactive that the ground it came from.

    • I've thought of ocean dispersal too. It certainly seems like it would be perfectly feasible from a technical standpoint. Encase it in small (granite?) pellets of some sort and disperse it a bit at a time throughout the oceans.

      But holy hell, the environmentalists would have a field day with that one. Can you imagine the outcry about how we just decided to "dump all our nuclear waste in the ocean". Do you remember the breathless headlines about detecting radiation in the ocean from Japan's Fukushima react

    • What about slowly dripping it from a ship so it dilutes it into the ocean

      Yeh, sure. Go find some politicians who want at least a snowball's chance in hell of getting re-elected, and ask them to vote for your proposal. Good luck.

  • by HotNeedleOfInquiry ( 598897 ) on Wednesday June 03, 2020 @11:28PM (#60143478)
    Never has been. *Any* solution will be politically wrong to a small but very vocal minority.
    • by MrKaos ( 858439 )

      Never has been. *Any* solution will be politically wrong to a small but very vocal minority.

      Which is irrelevant because small but very vocal minority have no input to siting nuclear facilities as they have very specific requirements to place them.

  • Subduction. (Score:5, Interesting)

    by ktakki ( 64573 ) on Wednesday June 03, 2020 @11:48PM (#60143518) Homepage Journal

    Can we just throw this crap into a subduction zone? Along with all our garbage? And the Republican Party? And Rush Limbaugh? And all Slashdotters? Please?

    k.

    • by cusco ( 717999 )

      I was just going to suggest the same thing (well, about the waste anyway). It was actually one of the plans in the '60s, but was never implemented.

  • by Gravis Zero ( 934156 ) on Thursday June 04, 2020 @01:41AM (#60143720)

    You don't have to lock away nuclear waste for millions of years or even thousands of years. Isotope decay is exponential so after 200 years it's no longer a major hazard. Additionally, most can be reprocessed and we have projects in the works that can consume the stuff.

    Nuclear waste is not an engineering problem, it's a political problem because people are uninformed.

    • Comment removed based on user account deletion
      • That depends on the isotope, the exact conditions and even the fact that our assumptions are correct (nobody has been around for long enough to actually confirm those numbers).

        No, it doesn't depend on anything. Fission products are well know and we have in fact been around long enough to confirm these numbers.

        But even by assuming that 200 years is really the absolute limit, are you OK with that?

        Sure. There's lots of human made structures around that have survived more than 200 years so this is a relatively trivial problem.

        Bear in mind that we aren't talking about naturally-occurring radioactivity which isn't too dangerous unless you are very close to the source for long periods. We are talking about the radioactivity provoked as a by-product of nuclear fission processes, which is very dangerous and needs to be carefully treated for as long as required.

        No, the radiation is no different from natural processes than that from fission. Why would it be?

        To not mention the small detail of the future costs associated with all that containment which will have to be paid by the future generations. And that wouldn't be the result of an accident, a negligent behaviour or a short-sighted approach, but costs which are certain and which you are knowledgeably giving to your grand-(grand-grand-, etc.)children as a nice present.

        The radiation from fission products will be lower than that from naturally occurring materials after 200 years or so. We know this because we have

    • by MrKaos ( 858439 )

      Isotope decay is exponential so after 200 years it's no longer a major hazard.

      Inverse Euler expresses radioactive decay, IIRC.

      Nuclear waste is not an engineering problem, it's a political problem because people are uninformed.

      Usually uninformed about how bio-accumulation works and why it's a difficult engineering problem.

  • The scientists believe that calcium in the rock reacted with carbonate in the fluid to create tiny crystals of calcite that plugged all the gaps and prevented further flow

    Products such as Krystol https://www.kryton.com/product... [kryton.com] or Xypex https://www.xypex.com/ [xypex.com] or other concrete waterproofing also act as Self-Repair when it cracks very useful in watertanks addionally strengthen the concrete.

  • by MrKaos ( 858439 ) on Thursday June 04, 2020 @02:13AM (#60143758) Journal
    Ol Olsoc and I [slashdot.org] were discussing this last year and how Yucca mountain in contradiction of Title II of the Nuclear Waste Policy Act of 1982.

    The DOE's original specification for a waste storage facility was granite and bentonite clays.

    • by MrKaos ( 858439 ) on Thursday June 04, 2020 @02:25AM (#60143788) Journal

      Also here is a link to the Swedish facility [geoprac.net] that was recently complete and now operational [skb.com] built in granite.

    • by MrKaos ( 858439 )

      Also discussed here in relation to the EROEI [slashdot.org] and the amount of peta joules of energy used to construct conventional facilities and how using granite may reduce the energetic input of the nuclear industry.

  • Synroc ("synthetic rock") was developed for this purpose by Australian scientists. I remember reading about it back in the 1970s, seems like it's perfected now
    https://en.wikipedia.org/wiki/... [wikipedia.org]
  • Granite storage is a band-aid that tries to hide the symptom, and not fix the problem.
  • by kriston ( 7886 ) on Thursday June 04, 2020 @09:58AM (#60144676) Homepage Journal

    Why not reprocess it?

    Why is the US still following the anti-proliferation policies of the Jimmy Carter Administration?

  • Almost a hundred posts and no bad puns about this? And no innuendos about a body part being as hard as granite? What's this world coming to?
  • by pyrrho ( 167252 ) on Thursday June 04, 2020 @11:16AM (#60145002) Journal
    ... by using the "waste" as fuel since 90% of the energy is still in the "spent" rods.
  • by rnturn ( 11092 ) on Thursday June 04, 2020 @11:37AM (#60145076)
    ... the granite countertop industry. Several TV channels devoted to house flippers will have to cease operation or resort to nothing but reruns.
  • Oklo, Gabon has a natural nuclear reactor running, and it's apparently perfectly safe...except for the mutants in the area, of course.

    https://en.wikipedia.org/wiki/... [wikipedia.org]

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