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Science

The Next Graphene? Shiny and Magnetic, a New Form of Pure Carbon Dazzles (sciencemag.org) 36

sciencehabit quotes Science magazine: A "happy accident" has yielded a new, stable form of pure carbon made from cheap feedstocks, researchers say. Like diamond and graphene, two other guises of carbon, the material seems to have extraordinary physical properties. It is harder than stainless steel, about as conductive, and as reflective as a polished aluminum mirror. Perhaps most surprising, the substance appears to be ferromagnetic, behaving like a permanent magnet at temperatures up to 125 degrees C -- a first for carbon. The discovery, announced by physicist Joel Therrien of the University of Massachusetts in Lowell on 4 November here at the International Symposium on Clusters and Nanomaterials, could lead to lightweight coatings, medical products, and novel electronic devices....

The magnetism adds to a suite of properties never before seen together in a form of pure carbon. They include tremendous hardness that presumably results from the bonds joining adjacent layers: "We've tried scratching it with steel wool, and it comes off clean," Therrien says. "The only thing we can say verifiably scratches it is a diamond scribe." Though the group has yet to measure the tensile strength of the material, the fact that vanishingly thin flakes hold together at millimeter size suggest it may be as strong as some metals, he says. Then there is the mirrorlike appearance, seen in photos Therrien showed at the meeting. The team's measurements indicate that the film, even when just 50 nanometers thick, reflects more than 90% of incoming light at wavelengths ranging from the far-ultraviolet to the midinfrared. That attribute could make it a useful reflective coating, more durable than the standard aluminum, for mirrors in cameras and telescopes.

Its electrical conductivity turned out to be just shy of that of stainless steel. But it can also display other electronic properties. Annealing the material by slowly heating it to 1000 degrees C dims its shine and turns it into a semiconductor with a band gap -- the energy required to liberate an electron -- similar to that of amorphous silicon, which can turn light into electricity. That makes it a candidate material for photovoltaic cells, Therrien suggests.

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The Next Graphene? Shiny and Magnetic, a New Form of Pure Carbon Dazzles

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  • the first step. (Score:4, Interesting)

    by Gravis Zero ( 934156 ) on Sunday November 17, 2019 @07:27PM (#59424420)

    regardless of how well this particular form of carbon turns out, discovering a way to make many different allotropes [wikipedia.org] seems more important.

    Therrien is bullish about the long-term potential of geometrical frustration to synthesize novel allotropes of carbon and other elements. “Even if it works only for carbon, the very fact that there are probably hundreds of different allotropes that you might be able to make using this approach is going to really open things wide up.”

    BTW, this was yet another accidental discovery made by a scientist.

    Therrien says that on 13 November 2017, after teaching an evening class, he returned to his lab to check on his oven and noticed the smell of tar. The inside of the furnace was caked in black pitch. But the copper foil was covered in something that looked like polished silver.

    • Looks like they've just invented durasteel, we've already got ion drives, the star destroyers should soon follow. We can figure out how to build turbolasers later.
    • BTW, this was yet another accidental discovery made by a scientist.

      Therrien says that on 13 November 2017, after teaching an evening class, he returned to his lab to check on his oven and noticed the smell of tar. The inside of the furnace was caked in black pitch. But the copper foil was covered in something that looked like polished silver.

      There must be no better feeling for a research scientist than for a failed experiment to make you say, "What the fuck is going on here?"

  • The less mirrored version so it's super shiny but not blinding. Photovoltaic so I don't need to charge at home. Strong. Sounds like similar weight to everything else. Must have on car!
  • by Anonymous Coward

    There's all kinds of cool stuff happening all the time with pretty smart people going "who would have thunk that?"

    Science: Because no matter how hard you try, you aren't going to pray that rocket into space.

  • If they can scale it up, it would make a dandy coating for pans. Teflon is terrible for the environment, and produces toxics when overheated.

    I'm sure it would do a lot of more exotic and interesting things as well, but I was just reading about the evils of PTFE

    • It depends on how good it is at evenly spreading heat, for now, copper is king.
    • by skids ( 119237 )

      Before we all get too far ahead of ourselves...

      the fact that vanishingly thin flakes hold together at millimeter size suggest it may be as strong as some metals

      ...and as dangerous as asbestos?

  • to creating UFO's that you can't really see because of nearly complete reflections, that can recharge by hovering over power lines, and...

    Well, we're still working on the cow and human snatching part.

    But we have scientists working HARD on the problem!

  • Correction (Score:5, Informative)

    by burtosis ( 1124179 ) on Sunday November 17, 2019 @09:28PM (#59424720)
    Summary is now off:

    *Correction, 15 November, 11 a.m.: An earlier version of this story incorrectly suggested U-carbon was the first carbon allotrope to display ferromagnetism at relatively high temperatures, when in fact other forms of pure carbon have displayed that behavior.

    I apologize for RTFA, where do I turn in my slashdot cred?

  • Pretty sure the To the Stars Academy already has a piece of this.
  • One of the most interesting properties I see here is the fact that it is reflective in the ultraviolet range. I'm adjacent to (but not part of) to the EUV lithography industry and it leaves me wondering if this has potential applications in EUV mirrors.
  • From the article: " ... But rather than pumping in a feed gas of the usual small hydrocarbons, such as methane, he injected a more complex precursor: 2,2 dimethylbutane, a cheap petrochemical that is available by the ton. As a branched hexane, the chemical has six carbon atoms arranged along a bent backbone. .."

    2,2 dimethylbutane doesn't have a 'bent backbone' of six carbon atoms.

    The most you can trace is four.

    It branches to 3 identical methyl groups.

Every nonzero finite dimensional inner product space has an orthonormal basis. It makes sense, when you don't think about it.

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