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Science Technology

Graphene: Fast, Strong, Cheap, and Impossible To Use 187

An anonymous reader writes: We keep hearing about the revolutionary properties of graphene, an atom-thick sheet of carbon whose physical characteristics hold a great deal of promise — if we can figure out good ways to produce it and use it. The New Yorker has a lengthy profile of graphene and its discoverer, Andre Geim, as well as one of the physicists leading a big chunk of the bleeding-edge graphene research, James Tour.

Quoting: "[S]cientists are still trying to devise a cost-effective way to produce graphene at scale. Companies like Samsung use a method pioneered at the University of Texas, in which they heat copper foil to eighteen hundred degrees Fahrenheit in a low vacuum, and introduce methane gas, which causes graphene to "grow" as an atom-thick sheet on both sides of the copper—much as frost crystals "grow" on a windowpane. They then use acids to etch away the copper. The resulting graphene is invisible to the naked eye and too fragile to touch with anything but instruments designed for microelectronics. The process is slow, exacting, and too expensive for all but the largest companies to afford. ... Nearly every scientist I spoke with suggested that graphene lends itself especially well to hype."
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Graphene: Fast, Strong, Cheap, and Impossible To Use

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  • Now if only... (Score:5, Insightful)

    by Anonymous Coward on Monday December 15, 2014 @08:13PM (#48606143)

    we weren't already doing so many things we were once told were impossible.

    • Re:Now if only... (Score:5, Insightful)

      by Crashmarik ( 635988 ) on Monday December 15, 2014 @09:26PM (#48606511)

      I'll see your impossible things and raise you "Things that will change the world" but have never been heard from after the initial hype.

      • Segway is the future of transportation.
        • This is happening, just not at the pace you expected after falling for the hype.

          It is a growing market, with lots of competition: https://ws.elance.com/file/Mar... [elance.com]

      • by aliquis ( 678370 )

        At least my bread was baked in my bread baking machine this morning.

        (No it wasn't.)

      • by geekoid ( 135745 )

        With the subtle difference in that we know a many. many ways graphene, and will change the world. There are application waiting for it.
        Graphene isn't the issue, manufacturing it cheaply is.

        I have n doubt someone will figure out how to manufacture it cheaply.
        This is like conversation I had about the blue LED 25 years ago. We knew we could do a lot with it. We knew what would change. WHat wasn't known was how to do it cheaply.

      • How about things that were hyped as world changers when they appeared, turned out to be impossible at the time, and quietly put into practice a couple of decades later, after they hype died down? They're often not world changers when they become successful.

  • Mass production ? (Score:5, Informative)

    by SteveAstro ( 209000 ) on Monday December 15, 2014 @08:36PM (#48606255)

    And yet, I read about a team in Cambridge in the UK who have a new low temperature process that can create graphene in industrial quantities.

    http://cambridgenanosystems.co... [cambridgenanosystems.com]

    • Re: (Score:3, Funny)

      by kelemvor4 ( 1980226 )

      And yet, I read about a team in Cambridge in the UK who have a new low temperature process that can create graphene in industrial quantities.

      http://cambridgenanosystems.co... [cambridgenanosystems.com]

      Do you expect the New Yorker to do actual research (or even a google search) before writing an article or something?

      • by Geoffrey.landis ( 926948 ) on Monday December 15, 2014 @08:51PM (#48606349) Homepage

        And yet, I read about a team in Cambridge in the UK who have a new low temperature process that can create graphene in industrial quantities. http://cambridgenanosystems.co... [cambridgenanosystems.com]

        Do you expect the New Yorker to do actual research (or even a google search) before writing an article or something?

        That was covered in the summary:
        "Nearly every scientist I spoke with suggested that graphene lends itself especially well to hype."

      • by Headw1nd ( 829599 ) on Monday December 15, 2014 @10:57PM (#48606897)
        The article actually seemed well researched, and involved interviewing or questioning at least a dozen people in the field. I'm pretty sure they used google somewhere in the process. I realize it's hip to bash reported for lack of thoroughness, but your comment seems out of place, as the New Yorker is not usually one to skimp on research.
      • The New Yorker has very good factcheckers. Maybe they don't work on everything (they don't, articles that get them in trouble get priority) but their reputation on factchecking is excellent.

    • Those are very small pieces of graphine. It is more like the tiny industrial diamonds that were initially produced. Most of graphine's use is when larger sheets can be made.

      • And from the tiny diamonds before we can now grow large gem quality ones. Same with Graphene, and a long way from the Samsung process.

    • by Headw1nd ( 829599 ) on Monday December 15, 2014 @10:48PM (#48606863)
      Did you read the article? In it they talk about a process to make graphene from anthracite coal with a 25% yield rate. The problem is not making graphene, any idiot with a pencil can do that, it's making large sheets of graphene. They go over this more than once. You really didn't read the article, did you?
    • Learn something new every day.

    • by reverseengineer ( 580922 ) on Monday December 15, 2014 @11:54PM (#48607089)

      Mass production- of graphene powder. Cambridge Nanosystems' process makes flakes of graphene in the 200-800 nm diameter range; cf. this interview [graphene-info.com] with their chief scientist. It's still a valuable material with many potential uses; that interview talks about composite materials and conductive inks. However, it's a very different product with different applications from a large-scale monolayer sheet.

  • wimpy talk (Score:5, Insightful)

    by iggymanz ( 596061 ) on Monday December 15, 2014 @08:41PM (#48606283)

    it's just an engineering challenge. in the late 19th century, people would have scoffed at the idea of an electrical device with over 4 billion components in a few square centimeters that was mass produced.

    Or imagine the most esteemed scientist of that day being told that a 200 meter long submarine vessel with a crew of 150 could be made with a power plant that only needed refueling every fifteen years, and that it could go for months underwater without surfacing, with weapons sufficient to destroy dozens of large cities.

    • Re: wimpy talk (Score:5, Insightful)

      by jd2112 ( 1535857 ) on Monday December 15, 2014 @09:24PM (#48606497)
      Yeah, nobody took that Jules Verne guy seriously.
      • So what you're saying is in a hundred years my grandkids will be happily living their lives as ghosts in the machine and/or megaflocks of nanomachines?
    • by Anonymous Coward

      Well, the Great Eastern was 211 meters long and it was built by 1858. Pretty sure those engineers would have been more open-minded. Maybe you need to talk to different people when you time travel to the 19th century and pretend to talk for all of them.

      Talk to Isambard Kingdom Brunel next time maybe?

      • I have shocking news for you from the 19th century, they inform me that the Great Eastern could only become a submarine vessel after sinking, what with it being a surface steam ship and all

    • Re:wimpy talk (Score:5, Interesting)

      by MattskEE ( 925706 ) on Monday December 15, 2014 @09:47PM (#48606605)

      Graphene in addition to the engineering challenges does have some very fundamental scientific challenges as well.

      The most important challenge is its lack of a bandgap meaning that graphene transistors cannot be turned off. That drawback means that while it may have a ~500GHz cutoff frequency on par with silicon and below the InP records it will not modulate current in an energy-efficient way, and while it can create some forms of logic the lack of a bandgap limits its power amplifying frequency to a measly 50GHz, well below the competing technologies. Contrast that with Northrop Grumman's recent 1000GHz amplifier [darpa.mil], which is admittedly not a great amplifier since it is run very near its cutoff frequency it has 1dB or less gain per stage, but it works which is still quite impressive.

      So far the various methods that can give graphene a bandgap also take away the extremely fast electron transport properties that made graphene so interesting for electronics in the first place. Some of us working on competing technologies wonder why hundreds of millions of dollars have been spent on graphene transistor development without solving the fundamental bandgap problem - of course we just want that money directed to our own research, but some of us try to be realistic about the capabilities of what we are developing ;-)

      I'm sure graphene will be useful for some things but so far there are still some fundamental problems that need to be solved before using it for high-speed electronics for wireless applications or digital logic. We'll see how it does.

      • forget transitors, they're so 20th century. Quantum dots and such, that's a better use for graphene

    • it's just an engineering challenge. in the late 19th century [...]

      So what you're saying is that in a couple hundred years, we'll have cracked it.

    • by Mr.CRC ( 2330444 )
      Only scoffed?
    • So where are our flying cars? We want our flying cars.

      • that was done in 1949, that Aerocar and other flying cars since then of course require a pilot's license. The market figured it's just better to just buy a damn plane and leave it parked at the airport.

  • by stephencrane ( 771345 ) on Monday December 15, 2014 @08:45PM (#48606311)
    Ah, yes, the New Yorker - when i need someone to cut through the latest scientific controversies, there is no finer swordsman.
  • by Anonymous Coward

    https://www.youtube.com/user/RobertMurraySmith
    I will just leave this channel here, that shows how easy it is to make it on small scale
    Also graphene oxide can be turned into graphene with just laser from lightscribe-enabled dvd burner -.-
    Also not every application requires high-purity/quality graphene

  • Materials and Process Scientist and Engineers will continually evolve the processes making it more cost effective. As for the "hype" about Graphine why are companies jumping on-board to manufacture it? Much like industrial and gemstone quality diamonds, or even Carbon Fiber, eventually a process will be found and Graphine will find more uses because it'll be less expensive.

  • by kajong0007 ( 3558601 ) on Monday December 15, 2014 @09:07PM (#48606435)

    I'm a student at Rice, where James Tour teaches. First semester my freshman year, I made the mistake of trying to take Organic Chemistry with James Tour as my professor.

    That class proved to me that I was not, in fact, a chemical engineer.

    I switched to Computer Science the next year, but it always makes me laugh seeing Prof. Tour's name.

    • by techno-vampire ( 666512 ) on Monday December 15, 2014 @10:57PM (#48606895) Homepage
      That class proved to me that I was not, in fact, a chemical engineer.

      If so, taking it wasn't a mistake because it kept you from spending years learning something you weren't really cut out for. And, if you count in the tuition money you saved, it may have been the best thing you ever did while at Rice.
    • That's a pity, because chemical engineers usually leave the actual chemistry to the chemists. Chemical engineering is more about process design, process control, upscaling and debottlenecking. You mostly get the chemical process outlaid by the chemists and you "only" have to worry about everything around it. We have started to dabble with material design, but you can be a good chemical engineer without a profound understanding of chemistry. Chemistry is mostly about the basic "what" and "how" whereas chemic

  • Aluminium (Score:5, Interesting)

    by valkraider ( 611225 ) on Monday December 15, 2014 @09:18PM (#48606479) Journal
    "In the mid 1880s, aluminium metal was exceedingly difficult to produce, which made pure aluminium more valuable than gold.[51] So celebrated was the metal that bars of aluminium were exhibited at the Exposition Universelle of 1855.[52] Napoleon III of France is reputed to held a banquet where the most honored guests were given aluminium utensils, while the others made do with gold." http://en.m.wikipedia.org/wiki... [wikipedia.org]
    • And in the 50s we were going to be driving nuclear powered cars by now.

      • Re:Aluminium (Score:5, Insightful)

        by Jeremi ( 14640 ) on Monday December 15, 2014 @09:54PM (#48606639) Homepage

        And in the 50s we were going to be driving nuclear powered cars by now.

        And indeed, some of us are. If you drive an electric car and live near a nuclear power plant, you might be one of them.

        • by MrL0G1C ( 867445 )

          Oh, but it's not really nuclear powered because uranium is made in suns, so it's a solar powered car (sarc).

          • Re: (Score:3, Interesting)

            by visavillem ( 3812219 )
            Actually, the elements heavier than Iron are created in the Type I supernova explosions, so it's a supernova powered car.
            • by geekoid ( 135745 )

              No, it's a Big Bang powered car.

              That right, they are powered by the sheer idiocy of that show.

        • And indeed, some of us are. If you drive an electric car and live near a nuclear power plant, you might be one of them.

          The atom powered car, ship, train or aircraft as imagined in the late forties, fifties and sixties was powered by an internal nuclear reactor.

          The ideal would be a vehicle or a vessel that would never need refueling.

      • If only Napoleon III used Uranium utensils.

      • by geekoid ( 135745 )

        And that feasible and a couple where built.
        Sadly, radiation put an end on that! More precisely the humans lack of tolerance for radiation.

  • ...I mean, it's the miracle substance you can do anything with, so maybe you can use it to make graphene! :D
  • The same hype that graphene is made of...

    • well, graphene lends itself especially well to hype. Yet another addition to its extensive array fascinating properties.

  • Same old story (Score:4, Insightful)

    by BobandMax ( 95054 ) on Monday December 15, 2014 @09:53PM (#48606631)
    Every time a new discovery is made, legions of naysayers appear to tell us how it will not make a difference or is impossible to implement or too expensive or, well, you fill in the blank. Never underestimate the ingenuity of people wanting fame, wealth, professional success, better mate selection or whatever. Graphene will be whatever it will be. It was only a relatively few years ago that these same people, or their ilk, thought they knew everything there was to know about the well-explored element, carbon. The future will reveal itself in due course and those who predict utopia or disaster are both likely to be wrong.
  • Misleading title (Score:4, Interesting)

    by pahles ( 701275 ) on Tuesday December 16, 2014 @02:01AM (#48607337)
    From the summary: "The process is slow, exacting, and too expensive" and "too fragile to touch". Yet the title says its fast, strong and cheap...
    • In strength it is both.
      Graphene is incredibly strong for a one atom thick material. All other materials need far more layers of atoms to achieve the same strength.
      However: it is a one atom thick material. That means it doesn't have much absolute strength.
      And the strength of graphene is non-uniform. It is far stronger in 2 directions than in the 3rd one

    • It was pick one, and they picked "impossible to use".

  • by EnsilZah ( 575600 ) <EnsilZah@@@Gmail...com> on Tuesday December 16, 2014 @08:18AM (#48608193)

    Elon Musk can convert coal into graphene by squeezing it with his buttcheeks.
    But he won't, because he's too busy to run another company right now.

  • Tehy were a gold-rush in the late 1980s, but relatively few commercial products so far.

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