MIT Researchers Harness Viruses To Split Water 347
ByronScott writes "A team of researchers at MIT has just announced that they have successfully modified a virus to split apart molecules of water, paving the way for an efficient and non-energy-intensive method of producing hydrogen fuel. 'The team, led by Angela Belcher, the Germeshausen Professor of Materials Science and Engineering and Biological Engineering, engineered a common, harmless bacterial virus called M13 so that it would attract and bind with molecules of a catalyst (the team used iridium oxide) and a biological pigment (zinc porphyrins). The viruses became wire-like devices that could very efficiently split the oxygen from water molecules. Over time, however, the virus-wires would clump together and lose their effectiveness, so the researchers added an extra step: encapsulating them in a microgel matrix, so they maintained their uniform arrangement and kept their stability and efficiency.'"
Hopefully they aren't too effective.. (Score:5, Funny)
I can just see it now. Some of these get dropped into an ocean, multiply, and eventually deconstruct the majority of the world's water into oxygen and hydrogen. It's the end of the world!!
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kinda like ice-nine, but backwards?
Re:Hopefully they aren't too effective.. (Score:5, Insightful)
Screw the ocean, I'm plenty worried about me.
Am I not about 70% water?
Re:Hopefully they aren't too effective.. (Score:5, Funny)
No, I think you are approximately 90% FUD and 10% skin.
Re:Hopefully they aren't too effective.. (Score:4, Insightful)
No, I think you are approximately 90% FUD and 10% skin.
Old Romulan Proverb: "Humans are a waste of skin."
So where does that leave him?
Re:Hopefully they aren't too effective.. (Score:4, Funny)
I was thinking more along the lines of "Ugly bags of mostly water".
(http://en.wikipedia.org/wiki/Home_Soil)
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Yes, just like playing Joe Satriani backwards.
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Viruses can't multiply by themselves, they have no DNA. They'd have to infect something first and convince it to do the work. Since there probably won't be any fish left in the sea soon [bbc.co.uk], it isn't going to happen.
Re:Hopefully they aren't too effective.. (Score:5, Insightful)
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That's fine -- but 6.8 billion of us don't want to risk homo sapiens being on the "extinct" list.
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Homo Sapiens will either evolve into something (or several somethings) else, or die off entirely. Of course, we can argue that we've already managed to fuck up our own evolution pretty good; the number of our members who manage to breed despite incredibly crippling congenital diseases, tendency towards debilitating developmental diseases, or simply managing to survive their own ridiculous stupidity [southparkstudios.com] through advancing medical science, is staggering.
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You have to admit, it'd be one HELL of a bonfire...
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about 250 million years ago
And how many millions of years did it take to get back to normal? Do you think humans could continue to thrive for just one of those millions?
Re:Hopefully they aren't too effective.. (Score:5, Funny)
Didn't it take a VERY LONG TIME for repopulation to happen... ?
Well it couldn't have taken that long.. after all, the earth is only 6000 years old!
/me ducks
Re:Hopefully they aren't too effective.. (Score:5, Insightful)
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Does it matter? Those events were catalytic in creating the biosphere of today. If today's biosphere is valuable, we owe it to those events.
If today's biosphere is valuable and it took millions of years to make it that way since the last "event", then if we cause another such "event", tomorrow's biosphere won't be quite so valuable to us.
Re:Hopefully they aren't too effective.. (Score:4, Insightful)
Does it matter?
It matters to me. If tomorrow's biosphere doesn't support my existence, you can bet your ass that I care about the continuation of today's biosphere. It's nice that you support the grand scale view that ultimately, life will continue, but I'm kinda selfishly interested in the continued existence of me and that of my off-spring. Which, you know, happens to be the mechanism behind every life form that ever existed.
Re:Hopefully they aren't too effective.. (Score:5, Insightful)
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True. But Pandas are cute and Spotted Owls are not. So fuck those Owls I say! They need to be furry and cute for me to give a hoot.
Yes, but I would emotionally prefer to live. (Score:3, Insightful)
I'm no big tree hugger, but as an animal I have come to form an emotional relationship with the earth and I would prefer that while, we recognize that changes to come to the environment and biosphere, that, we not go around pissing on things all over the place either. Like, I don't think its entirely wrong to ask people to respect the world they live in. Like, I never understood how my fellow right wingers could be so up and up on God, and not ponder for a moment that the earth should be respected because
Re:Hopefully they aren't too effective.. (Score:5, Interesting)
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What? Of course viruses have DNA (or RNA) otherwise there would be nothing to replicate...
Of course, there is also the mimivirus, with 1,000 genes that produces its own virion factory in the cell, so that it doesn't even have to put its genes into the cell nucleus.
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Re:Hopefully they aren't too effective.. (Score:5, Interesting)
All viruses have either RNA or DNA. If it doesn't have DNA/RNA it's not a virus [wikipedia.org] (2nd para).
Viruses cannot replicate without a host cell. However, it's quite possible to create viruses that are replication defective and cannot replicate even given their natural host. This is not a 'mutation' that can be undone but the removal of the entire sections of the viral genome: the virus remains able to infect (capsid interactions) but cannot complete it's life cycle. Initial replication is done with specifically spliced crossovers in a susceptible host cell.
It's all quite safe, and forms the basis of using viruses for both vaccination and gene therapy.
Now that's over with:
WHAAAAAAAAAAA! PANIC! WE'RE ALL GONNA DIE!!
Re:Hopefully they aren't too effective.. (Score:5, Insightful)
first it's not the virus that is doing anything. it's just a scaffold. the virus just self-assembles the scaffold for you. the interior DNA / RNA is irrelevant.
that said, the design for the self assembly and display is in the virus DNA I believe. so given a host to express itself in, it could presumably reproduce this in the wild. it would not be any use to the virus. But you could imagine that some host cell might harness the virus to make hydrogen for it's own purposes.
So I suspect that if this gets loose in the wild that the virus won't keep this trait long enough for some host cell to adapt to taking advantage of it.
Re:Hopefully they aren't too effective.. (Score:5, Funny)
Just don't get any on your skin.
"Gas bag science researchers exploding with good news. Film at eleven!"
Re:Hopefully they aren't too effective.. (Score:5, Funny)
Even if viruses could reproduce without a host (they can't), when oxygen mixes with hydrogen, the hydrogen oxidizes (burns) instantly. The exhaust from burning hydrogen is water.
Sheesh, I knew that in the 7th grade. [slashdot.org] I almost got expelled from school for knowing it...
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A hydrogen and oxygen mix at room temperature won't burn -- you need a spark. It's easy to make the mix: put two electrodes (carbon?) in water with an inverted, water-filled tube above them. You can use two inverted tubes to collect the gases if you prefer.
(Any mistakes are my own. I'm remembering this from school. I'm sure I did the acid+metal = hydrogen + alkali experiment when I was 10 or 11, and the electrolysis of water a year later. In both cases we had to do the "standard test for hydrogen" -- it bur
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As for your near-expulsion, that's strange. I went to a private high school and on the recruitment night the chemistry lab had hydrogen ignition as one of the two major features - the other was blowing soap bubbles full of natural gas which we then ignited with a candle attached to the end of a dowel. It was 20 years ago, though.
Re:Hopefully they aren't too effective.. (Score:5, Informative)
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There has got to be a missing step (Score:4, Insightful)
It still takes energy to split the molecule, and it has to come from somewhere, even if viruses to the dirty work.
Re:There has got to be a missing step (Score:5, Informative)
They're using the virus to bring together the components and then using sunlight to power the split and the biological components. It's like photosynthsis with H20 instead of CO2. Kind of novel, but who knows if it'll work on an industrial scale. It's just a lab experiment for now.
read the article, energy comes from the sun (Score:2)
They're basically doing a form of artificial photosynthesis.
Hollywood, are you listening? (Score:5, Funny)
Despite the self-limiting nature of the technique they describe, whether it ends up working in production or not, I guarantee you that, in a matter of days, someone is going to be flogging a script around Hollywood studios about a runaway virus destroying all the water on earth and the team of hot, young scientists who save the day at the last possible minute by using something compounded from randomly selected Greek and Latin roots.
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they're going to have to make mine first
it's about a virus that mutates into other viruses and the team of young, hot scientists (i see angelina jolie as their mentor, Doctor Y) can only stop it by developing a virus to infect the virus ...half tempted not to post this, because now that i think of it, it's a killer idea for a spec script...
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*gasp* they resort to polyamory??? FIENDS!
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Despite the self-limiting nature of the technique they describe, whether it ends up working in production or not, I guarantee you that, in a matter of days, someone is going to be flogging a script around Hollywood studios about a runaway virus destroying all the water on earth and the team of hot, young scientists who save the day at the last possible minute by using something compounded from randomly selected Greek and Latin roots.
I predict that they will have to create a hyper-velocity neutron star supernova with quanum entangled quibits that will irradiate the viruses.
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The Germ-eshausen Professor. Heh.
huh? (Score:2)
They also need to find a way to transform the products of the reaction into usable hydrogen fuel – currently the hydrogen atoms are split into constituent protons and electrons that must be recombined into complete atoms and molecules.
What's up with this? Last time I checked, a naked proton will find an electron, combine into hydrogen and then form up with other hydrogen atoms into H2 spontaneously. Perhaps, they meant the hydrogen spontaneously recombines with the Oxygen released when water is split.
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A "naked" single protons is always a hydrogen atom regardless of the presence or lack there of of an electron.
They're quite electrically unstable and will bind to just about anything with a free electron or two to spare. Not just other hydrogen molocules.
Right, but... (Score:2)
... this still seems like a pretty trivial problem to solve. I would imagine that the vast majority of these free protons would more-or-less immediately hook up with a passing water molecule to form a hydronium ion. Put a pair of electrodes in the water, run a small amount of current through it. The H3O+ ions will be attracted to the negative pole, start soaking up electrons, and... instant hydrogen, right? And the amount of electricity required would be way less than straight up electrolysis, since the onl
Is this basic, applied or vaporware research? (Score:5, Interesting)
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They also need to find a way to transform the products of the reaction into usable hydrogen fuel – currently the hydrogen atoms are split into constituent protons and electrons that must be recombined into complete atoms and molecules.
That doesn't make too much sense, but if it's correct, they are splitting water into mono-atomic hydrogen and mono-atomic oxygen, which will spontaneously recombine into H2O if it's not kept separated. Keeping the hydrogen and oxygen separate is a big problem. (without expending more energy to push stuff through barriers.)
No, they harness catalysts to split water (Score:5, Informative)
The actual splitting of water is done by using a pigment to absorb sunlight, then transferring the energy to indium oxide as a catalyst to split water. That's old news. Good, but old.
The problem is that it's hard to keep them doing this efficiently; things tend to clump up. They came up with a way to use viruses to make a structure that keeps everything separate. Viruses are good for building self-assembling structures; this is also old news in nanotech.
Putting it all together here, that's news, but not terribly exciting news, since it's all still in a lab and not scaled to industrial sizes. So the PR department buffs it up with a misleading headline about viruses splitting water.
So no, you don't have to worry about the virus eating the world. It's all about indium oxide, which is not self-replicating. The viruses are just a piece of the machinery.
Re:No, they harness catalysts to split water (Score:5, Funny)
Hey, this is Slashdot. Stop depressing us with your world's-not-going-to-end attitude.
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This little comment of yours is more informative than the article which was originally linked to.
It also does not contain nonsensical statements like this:
"Splitting water is one way to solve the basic problem of solar energy: It’s only available when the sun shines."
Re:No, they harness catalysts to split water (Score:5, Informative)
Minor correction: they're using iridium oxide. That alone make it hard to scale up: iridium (virtually tied with osmium) is the densest material possible on earth that we know about, has an incredibly high melting point (900 *C higher than iron, though less than tungsten), and rare enough and hard enough to process to make it relatively expensive. They're using it in the lab because its a very good catalyst (see the rest of the platinum group).
But fortunately, almost all major advances start out this way: a small process that wouldn't work in real life, but which is later developed with other materials or techniques to scale up production. Unfortunately, many more end up as vaporware. Either way, even small advances like this are exciting.
It is really a sunlight + water - hydrogen device (Score:5, Informative)
Before anyone more think this will split water molecules magically. It also requires a catalyst, so it will not spread by itself in the ocean.
Missing totally from the article, is any hard numbers about efficiency. Is it converting solar energy at 1%, 10%, 20% ? How is compared to PV-cells? If it is anywhere near, it could be very neat to get your solar energy as hydrogen instead of electricity. Hydrogen can be stored and converted to electricity when you need it.
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How is this informative? Where's the car analogy?
am I missing something? (Score:2)
In the article its says they split hydrogen into protons and electrons that need to be recombined into atoms and molecules..
Am I missing something basic about chemistry and physics or are the writers of the article just mucking up the information? Aren't they just splitting hydrogen from oxygen using H20 as the "fuel" and sun light as the energy?
This is solar energy (Score:5, Informative)
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Translation: we looked at plants, and decided that trying to use some kind of bio lattice with catalizers on top to utilize the energy of sunlight to convert something common to something useful seemed like a good idea.
will make a great Cat's Cradle - like SF story. (Score:2)
Virus multiplies, converts *all* water on the Earth into a hydrogen ... All life on the Earth disappeared except for the hydrogen-powered vehicles which evolve into intelligent beings.
Desalination (Score:5, Interesting)
Am I missing something, or wouldn't this be a huge benefit to the existing process of extracting drinkable water from sea water? One of the major problems with the current process is the energy costs. If this is a low energy way to separate the hydrogen and oxygen, it would be easy to filter and much less energy intensive to recombine.
Parting water molecules (Score:5, Funny)
Mopping up (Score:2)
Hydrogen Economy is Vaporware (Score:2)
Regardless of the efficiency of this method, the hydrogen economy is still vaporware.
Hydrogen remains an energy transport, or store, not a source. You can't yet store enough practically to make a useful road vehicle. You lose energy manufacturing it electrically. You lose energy converting it back to electricity.
The current largest source of hydrogen? Oil. I'm sure you can wring it out of coal as well. The fossil fuel lobby love hydrogen technologies because they are the biggest source of hydrogen.
Solve the
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As sucky as hydrogen is, it could still be a reasonable transportation fuel.
What it would take is a lot of very, very, cheap electricity, the kind which might be generated through a series of thousands of small and medium sized hydropower stations built alongside (but not in) America's rivers and stored in the recently mentioned sulfur sodium batteries (http://hardware.slashdot.org/article.pl?sid=10/04/07/022250). Using this proven, if unexciting technology, enough power could be generated to create hydroge
Perpetual Motion ... (Score:2)
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You’re right, and I’m one of the first to cry foul when somebody starts touting hydrogen as the miracle fuel. “Just split water,” they claim, “and you can get as much hydrogen as you need!” And yes, they usually fail to recognise that splitting water in the first place requires more energy than burning the hydrogen will produce (yes, more: you’ll never do it 100% efficiently).
Usually.
Solar cells harness the sun’s energy and convert it to electrical energy, but
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M13? (Score:3, Funny)
I didn't know that was a bacterial virus, I thought it was a plant. Who knew? Wow!
Imagine this headline in Soviet Russia (Score:2)
In Soviet Russia Viruses Harness MIT Researchers To Split Water.
I don't know why, I must be really sleepy to go for the old 'Soviet Russia' gig and not with a better suitable naked and petrified Natalie Portman is pouring hot water splitting Viruses down MIT Researchers Pants.
Oh .... this is bad.
And here's the wrap-up... (Score:2, Informative)
“Unlikely”? That’s quite an understatement.
For perso
Am I the only one... (Score:2)
Am I the only one that whenever they hear of these types of technology (virus batteries, gmo food, virus water molecule splitting), gets the Devo song Mongoloid [ilike.com] streaming to their brain????!!!
Maybe this isn't new... (Score:2)
Congradulations (Score:5, Funny)
So congrats, you owe yourself a beer. Now get back to work.
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from the sounds of it, without the proper conditions it will clump up and stop functioning. Still, caution would seem to be the best possible idea.
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If the net effect is a positive for the virus, the behavior would have evolved on it's own in nature. If it's a negative, the virus will be out competed by other viruses. Even if it's neutral, it will at most fulfill its current niche and the water splitting abilities will be lost to genetic drift since it doesn't convey any advantage. In other words: Nothing is going to go wrong, control your irrational fears of genetic engineering and biotechnology.
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If the net effect is a positive for the virus, the behavior would have evolved on it's own in nature.
Evolution does not guarantee that any given mutation will occur.
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Sure, except for this bit:
Over time, however, the virus-wires would clump together and lose their effectiveness, so the researchers added an extra step: encapsulating them in a microgel matrix, so they maintained their uniform arrangement and kept their stability and efficiency.
If this virus ever got loose it would no longer be inside the microgel matrix, so it would soon lose its efficiency at generating hydrogen, becoming just another virus among many—and one ill-adapted to survive outside a lab.
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Re:What could possibly go wrong? (Score:4, Insightful)
1. it's not self-catalyzing, it takes iridium oxide which is what you might call highly uncommon (though they implied there might be others, but if they needed to start with Ir02 the list must have been very very short)
2. they didn't say under what conditions it reproduces, but i wouldn't be surprised if the open ocean isn't its best culture medium, or even a decent one
3. in order to get it to work for any sort of duration they had to encase the virus in a gel. now, unless they plan to mutate the virus to produce its own gel, or not to need the gel, it's not going to threaten very much of any body of water
4. we could use a little more oxygen, as ours is being bound up into CO2 by people who persist in believing that burning coal & oil is a god-given right
Re:What could possibly go wrong? (Score:5, Funny)
Re:What could possibly go wrong? (Score:4, Insightful)
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Re:What could possibly go wrong? (Score:5, Funny)
Perhaps they could use light as the energy source required. You could even make sugar with it! But you'd need to collect the sunlight - since red and blue are the highest-energy colors, it would need to be a green pigment.
If only such a thing existed...
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In this zombie-apocalypse scenario flamethrowers will be very dangerous to use!
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Actually the water in the zombies will all get broken down into hydrogen and oxygen so we're good.
My new car runs on zombies!
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FYI the people who write zombie movies aren't scientists either.
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I've never heard something like this, is it half alive?
They mean a virus that typically infects bacteria.
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It infects bacteria.
Like a canine virus infects dogs.
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Re:Personally... (Score:5, Insightful)
Please STFU. You paranoia is sourced in horror movies and cheap sci-fi novellas. Go read about real microbiology. Thanks.
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Re:What could ... (Score:5, Informative)
Impossible. You need energy input to split water. No amount of catalysts can help you - first law of thermodynamics comes to rescue, as usual.
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Re:What could ... (Score:5, Informative)
Now the second law comes to the rescue - you need temperature gradients to extract energy.
Re:What could ... (Score:4, Funny)
Since the viruses use sunlight to convert water, all we would need to do is to stay in a dark room.
A large tin foil hat can also be used.
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It is self limiting.
If you can't keep the hydrogen and oxygen separated they will just reform as water again perhaps killing the virus in the process.
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A) Tell that to an anaerobic organism.
OR
B) philosophical question: Is the global firestorm, caused by a spark igniting the H and O mixture, toxic?