Cheaper, Cleaner Hydrogen Without Platinum 295
keithww writes "Looks like the hydrogen economy may have gotten a whole lot cheaper. Wisconsin team engineers gas from biomass
using common metals of tin, nickel, and aluminum instead of platinum. This looks like a good way to get rid of biowaste also." Of course, there's still a long way to go before the automotive industry is using it, but it is good news nonetheless.
Never underestimate the power of a lobbyist (Score:4, Interesting)
Re:Never underestimate the power of a lobbyist (Score:3, Insightful)
Re:Never underestimate the power of a lobbyist (Score:4, Insightful)
The US is not the world (Score:5, Insightful)
Re:Never underestimate the power of a lobbyist (Score:3, Informative)
Some companies are better than others, for example BP (British Petroleum) have realised this, and decided to hedge their chips and are putting money into fuel cell research.
Re:Never underestimate the power of a lobbyist (Score:3, Insightful)
Ciao
Re:Never underestimate the power of a lobbyist (Score:2, Interesting)
The reason we use Petrochemicals instead of the green method of your choice is because we - the world - have a huge infrastructure in place to provide for this. If you want to start your own free/green energy distribution then fine, go ahead, the oil companies won't stand in your way but you face a simple uphill battle of fighting what is cheap and available right now.
This is like those ads you see in the back of science magazines, saying they have plans for a 348mpg carburator and the only
Nah (Score:4, Insightful)
They'll encourage it. (Score:3, Insightful)
Re:Never underestimate the power of a lobbyist (Score:5, Interesting)
Re:Bush is also the coal industry (Score:2)
Don't forget Ashton Kutcher's recent admission to smoking out the Bush twins!
"Ashton & the Bush Twins Party On!" [etonline.com]
Re:Never underestimate the power of a lobbyist (Score:3, Interesting)
H2 is another energy market to be R&D'ed, tapped and then optimized for profit.
Exxon-Mobil is working GM and Toyota to use gasoline and methanol with fuel cells to avoid some of the complications with using just H2.
And in the industry, there is already a sense that they need to adapt in order to survive. When a former Saudi oil minister and petroleum consultant says..."Thirty years from now there will be a huge amount of oil - and no buyers. Oil will be left in the ground. The Stone
10 gallon gas per person per week mandate (Score:4, Insightful)
Right! Bush, Rumsfeld, and Cheney are going to mandate every American buy 10 gallons of gas every week to keep the oil industry afloat as the price of oil goes to $30, $40, $50, $60, $70 a barrel and the US has to increase its share of world oil production from 25% to 40% to 50% to 75%.
The reality is that world oil production will peak this decade if it hasn't already.
That doesn't mean that oil will run out, only that there will be no increase in daily supply no matter what the demand. There have been no major oil fields discovered in the past decade, and the important oil fields were discovered more than 40 years ago.
Technology won't magically cause oil to require less energy to extract. The people extracting oil aren't complete morons, they have always extracted the oil that is easiest and cheapest to extract before moving on to the harder and more expensive to extract oil. Millions of people have been extracting oil over the past century and if there was a way to extract hard to extract oil cheaper than today, they would have found it by now because cheaper would mean more profit.
So the only way the oil industry can prevent higher prices motivating consumers to switch to some other, any other, form of energy is to get a mandate passed that requires Americans to buy 10 gallons of gas every week no matter what the price.
Failing that, there is nothing that the oil industry can do to prevent the decline of oil as an energy source.
What we as consumers have to hope for is a million small steps to cheaper hydrogen production. The likelihood of someone coming up with real cold fusion are real slim. Hydrogen as a fuel in 20 years is going to be more expensive than oil as a fuel is today, but the price of oil in 20 years will make hydrogen look cheap.
do you know why are they called 'energy companies' (Score:3, Interesting)
The largest source of hydrogen today is the very same companies that sell you gas. You will still be filling your hydrogen car at a Shell station.
Re:Never underestimate the power of a lobbyist (Score:2)
Re:Never underestimate the power of a lobbyist (Score:3, Insightful)
If they can efficiently reform the gasoline into hydrogen IN THE CAR, we may not need to immediately rebuild our entire energy infrastructure. Then over time as we get better at producing ethanol, for example, from urban or agricultural waste, we can migrate to a more
Re:Never underestimate the power of a lobbyist (Score:4, Informative)
Cheaper hydrogen still! (Score:4, Funny)
Re:Cheaper hydrogen still! (Score:2, Funny)
Down with solar power! (Score:4, Funny)
Funny!
Many groups and individuals are proposing that our government spend tax money on research and development of systems to utilize solar energy. They urge construction of vast solar energy collectors to convert sunlight to electricity to supply our energy needs. They would even put solar collectors on roofs of homes, factories, schools, and other buildings. Proponents of this technology claim that energy obtained from the sun will be safer and cleaner than coal, oil, or nuclear energy sources.
We view these proposals with alarm. Unscrupulous scientists and greedy promoters are hoodwinking a gullible public. We consider it rash and dangerous to commit our country to the use of solar energy. This solar technology has never been utilized on such a large scale, and we have no assurance of its long-range safety. Not one single study has been done to assess the safety of electricity from solar energy as compared to electricity from other sources.
The promoters of solar energy cleverly lead you to believe that it is perfectly safe. Yet they conveniently neglect to mention that solar energy is generated by nuclear fusion within the sun. This process operates on the very same basic laws of nuclear physics used in nuclear power plants and atomic bombs!
And what is the source of this energy? It is hydrogen, a highly explosive gas (remember the Hindenberg?) Hydrogen is also the active material in H-bombs, that are not only tremendously destructive, but produce dangerous fallout. The glib advocates of solar energy don't even mention these disturbing facts about the true sources of solar energy. What else are they trying to hide from us?
In addition to the known dangers cited above, what about the unknown dangers, that very well might be worse? When pressed, scientists will admit that they do not fully understand the workings of the sun, or even of the atom. They will even grudgingly admit that our knowledge of the basic laws of physics is not yet perfect or complete. Yet these same reckless scientists would have us use this solar technology even before we fully understand how it works.
Admittedly we are already subject to a natural `background' radiation from the sun. We can do little about that, except to stay out of direct sunlight as much as possible. The evidence is already clear that too much exposure to sunlight can cause skin cancer. But solar collectors would concentrate that sunlight (that otherwise would have fallen harmlessly on waste land), convert it to electricity and pipe it into our homes to irradiate us from every light bulb! We would then not even be safe from this cancer-producing energy even in our own homes!
We all know that looking at the sun for even a few seconds can cause blindness. What long term health hazards might result from reading by light derived from solar energy? We now spend large amounts of time looking at the light from television monitors or computer screens, and one can only imagine the possible long-term consequences of this exposure when the screens are powered with electricity from solar collectors. Will we develop cataracts, or slowly go blind? Not one medical study has yet addressed itself to this question, and none are planned.
In their blind zeal to plug us in to solar energy, scientists seem to totally ignore possible fire hazards of solar energy. Sunlight reaching us directly from the sun at naturally safe levels poses little fire threat. But all one has to do is concentrate sunlight, with a simple burning- glass, and it readily ignites combustible materials. Who would feel safe with solar energy concentrators on their roof? Could we afford the fire insurance rates?
These scientists, and the big corporations that employ them, stand to profit greatly from construction of solar-power stations. No wonder they try to hide the dangers of the technology and suppress any open discussion of them.
Proponents of solar energy present facts, figures and graphs to su
Hydrogen from biowaste is stupid. (Score:3, Informative)
The only argument against methane is its mind alterating effects (halluzinations etc), so drug addicts might use it as a substitution for heroine and crack.
Re:Hydrogen from biowaste is stupid. (Score:2, Insightful)
It's also a gas at STP (Score:2)
So that's another argument against methane.
Yes (Score:2)
Re:Hydrogen from biowaste is stupid. (Score:4, Informative)
Also, you don't know that about the price. You can't possibly know the price of this process versus the price of methane extraction from biowaste.
I've personally heard something of the methane experiments and every one that I've heard about hasn't been able to produce enough methane from the waste to justify extracting the methane - it was always a very energy-costly operation that produced too little to be useful.
Do you have a link that says why methane is a better idea than hydrogen? Or any links for reversable methane reactions (this is one of the big deals for hydrogen? Burning hydrogen is an almost completely reversable reaction, so you can use it as a rechargable fuel source).
I'm willing to be convinced to the contrary, but from what I've heard about it, burning hydrocarbons doesn't seem to be as long-term or effective of a solution as burning hydrogen does.
Corrections (Score:2)
You can read more about this if you study rocket design. Hydrogen is lighter, but hydrocarbons allow you to use smaller fuel tanks for the same amount of energy. Methane is CH4, the lightest hydrocarbon.
Whether methane burns completely is a function of what's burning it. In a decently adjusted flame it burns to CO2 and water, with traces of carbon monoxide. The carbon monoxide doesn't have much effect on energy efficiency -- re
Re:Hydrogen from biowaste is stupid. (Score:2)
Yeah, but going to get more fuel would suck (Score:2, Funny)
Re:Hydrogen from biowaste is stupid. (Score:2)
I like pond scum [google.com].
Re:Hydrogen from biowaste is stupid. (Score:2)
Methane is a hydrocarbon, just like the octane you put into your car. So, like with all hydrocarbons, burning it produces all those nasty carbon-based greeenhouse gases everybody complains about
Re:Hydrogen from biowaste is stupid. (Score:2)
Re:Hydrogen from biowaste is stupid. (Score:2)
Re:Parent coment is stupid. (Score:2)
Re:Hydrogen from biowaste is stupid. (Score:2)
and the fact that methane produces carbon dioxide.
So does breathing.
Just think, once we come up with hydrogen cars we can tax bicyclists for causing global warming.
Ozone? (Score:3, Informative)
Re:Ozone? (Score:2)
Stop the leaks? Hah! Hydrogen leaks better than any other substance known (except maybe supercooled helium?). It goes right through steel (in the process, embrittling the steel).
Re:Ozone? (Score:2)
Re:Ozone? (Score:3, Funny)
Obligatory Link (Score:2)
Re:Ozone? (Score:3, Interesting)
http://edition.cnn.com/2003/TECH/science/06/12/hyd rogen.ozone.ap/
Where I went wrong was that sheep farts cause global warming, not destruction of ozone.
Re:Ozone? (Score:2)
Eat a Gyro!!!
DIHYDROGEN MONOXIDE! (Score:2, Funny)
Yes, you should be concerned about DHMO! Although the U.S. Government and the Centers for Disease Control (CDC) do not classify Dihydrogen Monoxide as a toxic or carcinogenic substance (as it does with better known chemicals such as hydrochloric acid and saccharine), DHMO is a constituent of many known toxic substances, diseases and disease-causing agents, environmental hazards and can even be lethal to humans in quantities as small as a thimbleful.
Research
Yeah, I gas from biomass too (Score:5, Funny)
Apparently I wasn't the only one to eat Taco Bell last night...
Re:Yeah, I gas from biomass too (Score:5, Funny)
Re:Yeah, I gas from biomass too (Score:2)
Kind of makes you want to avoid the burritos, eh?
Biomass (Score:4, Insightful)
Re:Biomass (Score:2)
bah...we should screww H and just use this (Score:5, Informative)
soylent green (Score:2)
Re:soylent green (Score:2)
Re:bah...we should screww H and just use this (Score:2)
Actually, it would be a very good idea for us to use biodiesel. You need a bit of methanol to begin the process but once you have done so you get some methanol out, supposedly, if you build a closed system and collect the methanol vapors. Biodiesel burns cleaner than diesel, and will actually remove carbon fouling deposits which diesel has put into your engine.
The other thing that comes out of the biodiesel cracking process is glycerine, which can be used to make soap, or fertilizer.
Of course, the bi
Re:bah...we should screww H and just use this (Score:2)
No it doesn't. What do the turkeys eat, exactly? Plants.
Plants -> Turkey -> Oil -> Pollution -> ???
I hope you're not claiming that you eventually recover all your plants, thereby resulting in the biological equivalent of a perpetual motion machine.
Burning oil certainly causes more pollution than burning hydrogen.
Carbon nanorods (Score:5, Interesting)
Or you could just store it as part of a liquid (Score:5, Interesting)
Pure hydrogen fuel cells sound like a great idea, no pollution but water.
Except then you come to the problem of storage and transportation and have to spend a truly massive fortune on research and development like this, and, once that's done you also have the job of upgrading the entire energy distribution infrastructure which oddly enough will also be rather expensive.
But hey, go ahead, it's a free market, someone else will come along with much cheaper solution.
obligatory back to the future post (Score:4, Funny)
anyone else get the image of doc brown tossing in some banana peels and beer into "mr. fusion"??
Mr. Fusion, meet Mr. Anti-Matter (Score:3, Insightful)
Whatever happened on research on anti-matter reactors? The entire concept is f
Re:Mr. Fusion, meet Mr. Anti-Matter (Score:4, Informative)
Gamma ray energy, that is.
Note also that antimatter annihiliates any matter it touches.
Core problem 1 is how to produce antimatter cheaply, and in enough quantity. Right now, it's only produced in particle accelerators.
Core problem 2 is how to transport it. If it's charged, you can use a magnetic bottle, but if it's not....
Core problem 3 is how to change the gamma rays into something useful. Gamma rays, you may recall, only interact with heavy metals (e.g. Pb) enough to really consider it. (Sure, they interact with, say, DNA, but not very often, compared to the number that get through unaffected). And even in things like Pb, it's only attenuated not stopped. The gamma rays might excite an electron, but that'll fall back to ground state, giving another gamma ray. It might interact with the nucleus, warming the substance a very little bit, but that's it. We don't have a good way of converting gamma rays into, say, heat to provide steam for traditional turbines.
Re:obligatory back to the future post (Score:2)
Why not both? If you're going for science fiction, why not extract the hydrogen from the biomass, sift out the deuterium and/or tritium, and fuse it?
cycle (Score:4, Interesting)
rus
Re:cycle (Score:2, Interesting)
Re:cycle (Score:2, Funny)
A better question: (Score:4, Funny)
48 hours... before what? (Score:3, Interesting)
Raney-NiSn can perform for at least 48 hours... before what? Before it has to be replaced? Before it has to rested? What happens after 48 hours?
Re:48 hours... before what? (Score:5, Informative)
Probably before the catalyst element corrodes too much that it needs to be replaced, as it's efficiency drops too much.
(most)Catalysts work by letting chemicals bind to them temporarily, before the chemicals go on to complete their reaction. In this case the biomass breaks into smaller chunks when it bind onto the catalyst and then the chunks are reduced further to produce the Hydrogen.
In a perfect catalyst, the catalyst would remain unchanged after the process. However some of the reaction products could get left on the surface of the catalyst (which physically blocks that bit of the surface ), also the surface could be deformed at a microscopic level (ie the atoms of the catalyst get moved about) which stops the catalyst from working as the chemicals are unable to bind to the surface.
Or it could just be catalyst in the EU hitting the working hour limit....
Re:48 hours... before what? (Score:5, Informative)
The catalytic activity degrades over time - but stabilizes at 72% of initial activity after about 48 hours of use. They published data out to 60 hours of use. (since I eat lunch with John & George on a semi-regular basis, I can find out Monday how far they actually tested, but for now that's the best I can tell you.)
So if you're wondering why the activity degrades over time, that's an easier and harder question to answer. It's easy, since it's one of a couple of likely culprits - impurities in the feed stream can poison (ie, react with) the catalyst; the catalyst might physically break down over time, the metals in the catalyst might rearrange themselves over time (like tin on the catalyst surface might migrate to the sub-surface), etc. The hard part is figuring out which one (or how many) of these things are actually happening.
And as an aside, I can't believe it's a story in
What is the process's efficiency (Score:4, Interesting)
Re:What is the process's efficiency (Score:2)
Stop recycling! (Score:5, Interesting)
No, I'm not kidding.
Global warming may be due to humanity's CO2 emissions, or solar radiation, or something we haven't even discovered yet, but it's something detrimental to our society and it'd be nice to do something about it. Well, the best way is to stop burning stuff, obviously. On the other hand, our society runs on our burning stuff. That's not good.
Well, the least we can do is stop burning stuff that gives us the least benefit. That, my friends, is garbage. Waste incinerators, even if they provide cogeneration, would run at a loss if they weren't paid extra by people who don't want the stuff they burn. So it's not such a big deal to NOT burn the garbage and burn something more efficient instead.
Further, while there are some materials it may make sense to recycle, when it comes to plastics, you're better off burying it. Every bit of plastic you DON'T recycle is another quantity of oil that will never be burned, but will instead go back to sequestering carbon under the ground.
Re:Stop recycling! (Score:5, Interesting)
Burning things that have been produced by recently living organisms is not too bad, it's just another part of the normal carbon cycle.
The problem with fossil fuels is that they are re-introducing carbon dioxide into the atmosphere that has been removed from the natural carbon cycle...
An interesting question is how efficient can we make energy production based on plant farming, which is an indirect way of utilizing solar energy - plants transform carbon dioxide (+ water + sunlight) into hydrocarbons, hydrocarbons are processed into non-fossil fuel and utilized - can this be more efficient than solar panels? I believe photosynthesis is a pretty efficient process, especially for fast growing plants, but this is something that hasn't (AFAIK) been tried on a large scale.
Re:Stop recycling! (Score:2)
The big question is, will doing so really provide a benefit to the planet's ecosystems?
Re:Stop recycling! (Score:2)
So if you are worried about global warming, you should still bury the garbage.
There is no shortage of room to bury stuff. That is a myth promulgated by the recycling industry and various environuts.
glass recycling especially. (Score:3, Informative)
Turns out its far better to simply bury it. When you recycle it, first it has to be cleaned with highly caustic and dangerous chemicals which must be barrelled after their use (toxic waste).
When you melt it down, it requires alot of heat. The energy to create that heat has to come from somewhere - most often natural gas burners. So recycling glass actually consumes large amounts of fossil fuel
Re:glass recycling especially. (Score:2)
Regarding heat and chemicals, after digging for new sand, you still have to melt it down, costing a similar amount heat, as well as cleaning the glass with caustic chemicals. I would guess that refining the sand to pu
Re:Stop recycling! (Score:2)
No platinum? (Score:2)
Cars... (Score:5, Insightful)
Isn't it, perhaps, the whole idea of an automobile, which is inherently inefficient, which needs re-thinking? It seems that support for rail over long distances, and metro-like systems for shorter distances might be more beneficial to all. Trains do not require huge streets, they do not require huge areas for parking, they do not lead to massive congestion, they do not cause deaths on a huge scale. (More Americans are killed every year from road fatalities than were killed in the war in Vietnam).
It may be that the car is too ingrained in the American psyche to dispense with it... but that's no reason to keep it either
Re:Cars... (Score:3, Insightful)
Believe it or not, there are still places in the US where you can drive for many, many miles without seeing another person, house / car / farm animal, etc... It wouldn't be economically feasible to run rails or buses out to these areas for the 1 passenger that you might get on a busy night. Besides that, even if you did have mass transit service to these areas, you couldn't run the things often enough to accomodate the schedules of the people that would utilize
Re:Cars... (Score:2)
While your comment is well-taken, it's less relevant than you think. The vast majority of our population is in dense urban areas.
C//
Re:Cars... (Score:2)
I think you also need to take into account large suburban areas, otherwise known as the land of yank-tanks and land-yachts. Most of these areas, while close to major urban centers, also do not have acceptable mass transit systems. Thus, t
Re:Cars... (Score:3, Informative)
Re:Cars... (Score:2)
Wrong, many of us do not. I live in Seattle, home of the perpetual traffic-jam. I used to live in Kansas City. If you live in a suburb in Kansas City, not only do you not have any mass transit, you don't even get remotely convenient access to bus service (or any at all!). I'm sure the two cities I've lived in are not the only exceptions.
When I take the bus to work here in Seattle, I only have to make one change to another line, and STILL i
Re:Cars... (Score:2)
False. My comment was regarding the population density comment of the prior poster.
C//
Re:Cars... (Score:2)
Other than being extremely unrealistic and impractical, nothing wrong with your suggestion. In fact, the areas of the country (like the Boston-Washington corridor) that are highly settled do tend to have much more in the way of rail service.
Re:Cars... (Score:2)
If an automobile is inherently inefficient, then why do people use them? Despite what your obviously oversized brain tells you, it's not because people are stupid. Automobiles are more convenient. You don't have to plan your schedule with hundreds of other people. You leave when you want. You return when you want.
Automobiles may cause deaths on a huge scale, but they also save lives on a huge scale. When you need to go to a hospital you don't sit around waiting for a bus, do you? Sure, you could tak
Course, I fancy an air powered car (Score:5, Interesting)
http://www.cyber-media.com/aircar/
Even less polluting than a hydrogen powered vehicle, the only exhaust is clean air. Ironically, the air is cleaner going out than going in because it has to be filtered before reaching the engine.
Forget the "hydrogen economy" for transportation.. (Score:4, Insightful)
That's not to stop the U of W's process from fueling a large number of fixed polluters. For example, the giant cooling plant (part of a co-gen facility) for the building I work in could benefit from some H2. Bring it on, just don't waste time trying to get it into cars & trucks.
I'll go back under my rock now...
hows it work? (Score:2)
Re:hows it work? (Score:2, Interesting)
Re:hows it work? (Score:2)
2HCl + Mg -> MgCl2 + H2
Mr. Fusion! (Score:4, Funny)
converts bio-mass to fuel for futuristic cars? i KNOW i've see that somewhere before!!!
still many problems with hydrogen (Score:4, Informative)
there are still a lot of problems to be solved with hydrogen:
in the meantime, let's improve battery technology, fuel cells, and develop pebble bed nuclear reactor technology...
Behold... (Score:4, Funny)
Behold the power of cheese!
Way behind the times, fellas (Score:3, Interesting)
Re:The day this goes through... (Score:4, Insightful)
That's capitalism for you.
This is the first time on Slashdot (Score:3, Funny)
Re:The day this goes through... (Score:2)
Hate to break it to you, but it hasn't and it won't.
Re:The day this goes through... (Score:3, Interesting)
Capitalism works for commodities. I don't think anyone has ever claimed that it works when some or all parties are legally forbidden (by copyright or patents) from selling the same product, so SO or M$ don't prove that capitalism is "broken", only that it's not applicable.
Recently it's been determined that Standard Oil before its breakup was actually selling its products for fair prices, amazingly enough. It's not clear whether
Re:The day this goes through... (Score:2)
there will still be dealerships to sell the vehicles, still be mechanics to fix them and most likely still fuel distribution centers as well.
The oil thing is an international relations problem and will always be something if NOT oil.
As others have said, its capitalism, evolve or die.
Re:The day this goes through... (Score:2)
Been there, still doing that. Where you been, boy?
Re:The Hindenburg, Mark II (Score:5, Informative)
Argh but I get tired of people using the Hindenburg as proof hydrogen is dangerous.
The Hindenburg burned because of the paint that was used, which is chemically similar to rocket fuel [carolina.com].
Hydrogen burns with an invisible flame. Watch the footage - it's not the hydrogen that's the big problem.
If I had to be in a car crash, I'd prefer a hydrogen car to do it in. Gas tank ruptures, hydrogen floats off. Gasoline lays in puddles underneath me.
Weaselmancer