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Researchers Discover That Sand Behaves Like Water 192

Posted by Soulskill
from the not-in-your-stomach dept.
Xeger writes "University of Chicago researchers have found that streams of sand can behave in a similar manner to liquids, forming water-like droplets when poured from a funnel. To obtain these results, they dropped their expensive high-speed camera from a height of several meters and observed the sand forming into droplets — something that shouldn't happen without surface tension. These findings suggest that conventional engineering wisdom about sand, dirt and other grainy materials needs to be rethought, and that it might be possible to apply fluid dynamics to some solids problems."
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Researchers Discover That Sand Behaves Like Water

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  • by samriel (1456543) on Saturday June 27 2009, @10:08AM (#28494467)

    Besides that, there is also the problem of the greater weight of the camera causing it to fall faster than the lighter grains of sand. Ideally, you'd want to observe the sand in as stationary and synchronized a manner as possible. However, if the camera is moving relative to the sand, it would be difficult to monitor any particular clump of falling sand.

    I have one word to say to you and just one word: Galileo. [jimloy.com]

  • Re:Yawn (Score:1, Informative)

    by Anonymous Coward on Saturday June 27 2009, @10:30AM (#28494619)

    Technically, aren't most processors running linux just baked sand?

  • Re:hmm... (Score:5, Informative)

    by JustinOpinion (1246824) on Saturday June 27 2009, @10:51AM (#28494729)
    For those with access, the actual scientific article is:
    John R. Royer, Daniel J. Evans, Loreto Oyarte, Qiti Guo, Eliot Kapit, Matthias E. MÃbius, Scott R. Waitukaitis & Heinrich M. Jaeger "High-speed tracking of rupture and clustering in freely falling granular streams [nature.com]" Nature, 459, 1110-1113 (25 June 2009) | doi:10.1038/nature08115 [doi.org].

    The associated "News and Views" (Summary) is:
    Detlef Lohse & Devaraj van der Meer "Granular media: Structures in sand streams [nature.com]" Nature, 459, 1064-1065 (25 June 2009) | doi:10.1038/4591064a [doi.org]

    The previously-held belief in the field was that this breakup into droplets could be explained by inelastic collisions between the grains. That is, all the sand grains are bouncing off each other, but because these collisions are inelastic (the two particles slow down a bit relative to each other with the collision) the grains will, statistically, aggregate into larger structures.

    However this new piece of work shows rather strikingly that the origin of the force is a very weak form of surface tension. In other words, the breakup into droplets occurs for the same reason as it does in water and other liquids... it's just the magnitude of the force that is much smaller. In addition to the high-speed photography the Slashdot summary mentions, they also used atomic force microscopy [wikipedia.org] to directly measure the nanometer-scale cohesive forces between particles. In water, surface tension arises from the (rather strong) cohesive forces between water molecules (each water molecule 'sticks' to its neighbors). In sand, it appears that a very weak nano-scale cohesive force is nevertheless enough to generate macro-scale droplets out of micro-scale particles. The cohesive forces in sand arise from the weak Van der Waals [wikipedia.org] forces (weak, but universal, surface attraction), and due to capillary forces. That is, ambient water bridges the sand particles and causes what is effectively an attractive force, which leads to an effective surface tension.

    In the paper, they describe how they vary the particle type and ambient conditions, to demonstrate that these two effects are important. For instance varying humidity alters the cohesion and thus droplet formation. Also, altering the sand particles has an effect: e.g. rougher particles cannot stick to each other as much, thereby reducing this effect.

    This is a neat piece of work because it involves just "known" physics. It is demonstrating that well-established physical effects (surface forces and capillary forces) can explain phenomena where their effect was previously assumed to be negligible. The surface tension in these granular media are about 100,000 times smaller than water, yet the exact same effects are observed: the surface tension, weak as it is, tries to minimize surface area. Coupled with well-known instabilities [wikipedia.org], this causes a breakup into droplets.
  • Re:hmm... (Score:5, Informative)

    by JustinOpinion (1246824) on Saturday June 27 2009, @11:07AM (#28494835)
    The researchers did consider the effect of air. In fact, the ambient air has the opposite effect: the drag of the air as the droplets fall rips grains out of the droplets, thus working against whatever effect is aggregating them. In particular the authors say in their article [doi.org] (p. 1111):

    For a rough estimate of the cohesive strength we track clusters as they fall and accelerate to a speed at which Stokes drag pulls individual grains off cluster protrusions. Correcting for slight changes in the air viscosity at reduced pressure, this gives values of a few nanoNewtons.

    They then go on to measure more careful the strength of the clustering force, and ascribe it to both Van der Waals interaction and capillary forces. They did perform the experiment as a function of humidity to test the effect of water bridging (capillary forces) and found it to be significant. But they provide further data suggesting that Van der Waals forces also play a role. Again from the article (p. 1112):

    It is difficult to distinguish van der Waals from capillary forces because we cannot rule out molecularly thin absorbed films that create tiny bridges between individual asperities24,25. However, we still observe clustering in glass grains stored under vacuum (0.05 kPa) at low humidity (,1%) and also in grains coated with hydrophobic silane.

    The fact that clustering still occurs in vacuum suggests air is not crucial to the effect. The precise scaling they observe (e.g. the size and separation of the clusters as a function of time) is not consistent with simple inelastic collisions, and the effect of air would actually be to breakup the droplets, absent any attractive force. What they instead measured was a weak (but sufficient!) interaction between grains, which they ascribe to surface forces and capillary action.

  • Re:Meh... (Score:5, Informative)

    by JustinOpinion (1246824) on Saturday June 27 2009, @11:21AM (#28494943)
    Nope. The researchers thought of that, too. But they ruled-out electrostatic charging. From the article [doi.org] (p. 1111):

    In principle, cohesion might arise from a variety of sources, including electrostatic charging, capillary or van der Waals forces. ... a rough estimate of the cohesive strength ... gives values of a few nanoNewtons. To compare this to any electrostatic forces present, we obtain the distribution of charges on the grains by applying a uniform electric field perpendicular to the falling stream and tracking individual grain trajectories (see Supplementary Information). For both glass and copper, we find the streams are neutral overall but contain a small fraction of positively and negatively charged grains, up to a roughly q_max = +/- 100,000 electron charges per grain (Supplementary Fig. S2). Still, this gives attractive electrostatic forces a maximum F_max = (1/4*pi*e_0)q_max^2/d^2 ~= 0.1 nN for grains with diameter d = 100 micrometer, too weak to be the dominant cohesive force. (Here e_0 = 8.85 * 10^-12 C^2 N^-1 m^-2 is the permittivity of free space.) Furthermore, experiments with conductive, silver-coated 100-micrometer-diameter glass spheres produce clusters identical to experiments using uncoated spheres, emphasizing that electrostatic forces do not drive the observed clustering.

    (Note that I rewrote the equations in plaintext since Slashdot doesn't support all the necessary characters.)

  • Not quicksand (Score:5, Informative)

    by rlseaman (1420667) on Saturday June 27 2009, @11:27AM (#28495001)

    Quicksand discovered !!!

    Quicksand is rather a colloidal suspension requiring an underground water source:

    http://en.wikipedia.org/wiki/Quicksand [wikipedia.org]

  • Re:It's the air. (Score:5, Informative)

    by vux984 (928602) on Saturday June 27 2009, @11:36AM (#28495087)

    repeating the test in a vacuum would test this hypothesis pretty easily.

    And if you'd read the full article you'd know that they did test in a vacuum. And they still formed droplets.

  • Re:Not quicksand (Score:3, Informative)

    by Quothz (683368) on Saturday June 27 2009, @11:38AM (#28495117) Journal

    Quicksand is rather a colloidal suspension requiring an underground water source

    Not necessarily [wikipedia.org].

  • by Anonymous Coward on Saturday June 27 2009, @11:41AM (#28495133)

    physicists may have just figured this out but special effects guys have known about it for decades.

    With all due respect to special effects guys, they were aware of the phenomenon, but had no explanation. Physicists have also been aware of the phenomenon for decades. What this new work does is provide an explanation. From an explanation we can then move to understanding nature and rationally building technologies based on the knowledge.

    Again, props to the FX people for coming up with such cool solutions. But your comment makes it seem like all that is necessary is observation. Science is about much, much more. It is about reproducible observation, experimentation, modeling, explanation, theory, and understanding.

  • by nloop (665733) on Saturday June 27 2009, @11:59AM (#28495267)
    I thought the same thing, however, someone earlier posted a link to the original [doi.org] article, that requires a subscription to actually read, where apparently they say they tried it in a vacuum and achieved the same results
  • Re:hmm... (Score:3, Informative)

    by raynet (51803) on Saturday June 27 2009, @12:54PM (#28495663) Homepage

    Cannot get to the article you linked to, but the text you quoted doesn't say that they did the test in vacuum, just that they stored the sand in vacuum before testing it to get rid of any moisture.

  • Re:hmm... (Score:4, Informative)

    by JustinOpinion (1246824) on Saturday June 27 2009, @01:20PM (#28495825)
    Yeah you're right that quote was just about differentiating the contributions from van der Waals and capillary forces. Further in the paper they also explain:

    Whereas the instability of ordinary liquid columns is driven by molecular surface tension, possible mechanisms for droplet formation in granular systems include hydrodynamic interactions with the surrounding gas, inelastic grain-grain collisions, and cohesive forces. Hydrodynamic interactions have indeed recently been associated with fluctuations in the profile of streams falling in air 9; however, from experiments across a wide range of ambient pressures down to 0.03 kPa we find that grain-gas interactions do not drive clustering (Supplementary Fig. S1), in agreement with earlier work 6.

    (Emphasis added.)

    For anyone curious, reference 6 is:
    Mobius, M. E. Clustering instability in a freely falling granular jet. [aip.org] Phys. Rev. E 74, 051304 (2006). doi: 10.1103/PhysRevE.74.051304 [doi.org]

    If you don't have access to Phys. Rev. E., you can read a preprint of the same paper on ArXiv here [arxiv.org].

    That paper does measurements down to 0.03 kPa (1/5000 atmospheric pressure), and concludes:

    Clustering is observed down to the lowest pressure and the presence of air leads to larger clusters but does not initiate the cluster formation.

  • Re:hmm... (Score:5, Informative)

    by mosch (204) on Saturday June 27 2009, @02:50PM (#28496421) Homepage

    Had you read their research, you'd know that they tested this, and found it was not the case.

    Sadly, it's a lot easier to post snarky comments than it is to do the 3 minutes of research required to determine that the snarky know-it-all was, in fact, wrong.

  • Re:hmm... (Score:1, Informative)

    by Anonymous Coward on Saturday June 27 2009, @04:47PM (#28497527)

    Air flow around a cluster of falling particles has a scattering effect, and they *did* redo their experiment in a vacuum to be sure.

    However, we still observe clustering in glass grains stored under vacuum (0.05 kPa) at low humidity (,1%) and also in grains coated with hydrophobic silane.

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