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Science

Chemistry Sets for Adults? 322

An Anonymous Coward asks "I've been pursuing a few different lines of study, to refresh myself in basic sciences before I return to school. Right now I am reading up on Chemistry, and thought it would be fun to acquire a chemistry set just to play around with and maybe learn a few things from. Do any science geeks here have any suggestions?" My childhood garage probably still has purple and black stains all over it (lucky I was wearing glasses). 300 in one electronics kits, anyone?
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Chemistry Sets for Adults?

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  • For adults? (Score:5, Funny)

    by Anonymous Coward on Wednesday January 01, 2003 @11:50PM (#4996604)
    I hear those rolling methamphetamine labs are getting pretty popular.
    • Re:For adults? (Score:5, Informative)

      by Master Bait ( 115103 ) on Thursday January 02, 2003 @12:21AM (#4996743) Homepage Journal
      That dude shouldn't get just any chemistry set. He should ignore inorganic chemistry and go for the gold (organic chemistry). He needs to read Phikal [amazon.com] first. Then he needs to check out Rhodium [rhodium.ws] and The Vaults of Erowid [erowid.org] and a gander at The Lycaeum [lycaeum.org]
    • Too true, and this is precisely the problem. Too many chemicals out there can be used to make drugs and bombs, and that makes the government Very Unhappy.

      I loved chemistry in high school and regret i never followed it up. Actually the real life of a chemical engineer is probably equally boring as that of a computer programmer, but hey i can fantasize. Can't you just see the dinner party conversation? "Crank... um um um um yeah crank yeah crank don't got nothin on my hydropsychotic pseudomethephedrineactose-sulfate-2,4,5... that's like like 245 bpm heart rate and and and "
  • by packeteer ( 566398 ) <packeteer@sub d i m e n s i o n . com> on Wednesday January 01, 2003 @11:50PM (#4996608)
    So called "childrens" chemistry and electronics sets are perfectly good for adult too.
  • by MrLint ( 519792 ) on Wednesday January 01, 2003 @11:51PM (#4996609) Journal
    When i was in Orgo chem the *best* and coolest thing we did was extract limoene (orange oil). But you need reflux glassware for it.. but i'll tell ya the stuff smells great. and the practical upshot is that you can use it and other essental oils as food flavorings
    • limonene (Score:3, Informative)

      Uh, limonene [who.int] isn't a good thing to be eating.

      It smells fantastic, but it's a pretty potent solvent and can irritate the hell out of your digestive tract.
      • Re:limonene (Score:4, Informative)

        by MrLint ( 519792 ) on Thursday January 02, 2003 @12:06AM (#4996678) Journal
        Right from that page : Limonene is also used as a flavour and fragrance additive in food, household cleaning products, and perfumes. Im not advocating shugging this stuff straight. Butl ike with any extration of essential oil be it spearmint, peppermint, orange oil, of capsicum the idea it to not over use it.
    • Lucky. They always told us that we weren't supposed to lick the spoon.
    • OR.....you could sell it on tv and be the next Billy Mays(sp)
    • The notable exception. Just abou anything else you make in organic chem stinks to high heaven.

      People used to know when chem classes were in session just by the smell the lab experients leave on your hair and clothes.
    • by jayed_99 ( 267003 ) on Thursday January 02, 2003 @01:03AM (#4996861)
      *snickers* (Sorry, I was thinking of a time when I saw an idiot put a drop of pure pepeprmint oil on his tongue).

      I wouldn't advocate using most essential oils in food. You could use them in absolutely microscopic amounts -- but most kitchens/chefs don't have the tools, time or inclination to measure out correct amounts of essential oils. And leaving out the "potentially physically unsafe" part of it, essential oils are so strong in flavor and scent that they will easily overwhelm the other flavors in a dish.

      That's why most commonly used "food safe" extracts have an ingredient list that goes something like "distilled water, alcohol, whatever oil". The water provides a buffer.

    • Some time ago, my roommate bought a couple small bottles of this oil, thinking it was the kind you dip bread in. I didn't see why it wouldn't be; it sure smelled good.

      Yuck.
  • CBS (Score:5, Informative)

    by radiashun ( 220050 ) on Wednesday January 01, 2003 @11:53PM (#4996614)
    Carolina Biological Supply [carolina.com] has a bunch of learning kits, books, and software that would probably help you out. We get most of our lab supplies through them.
    • Re:Chemistry Set (Score:5, Informative)

      by Anonymous Coward on Thursday January 02, 2003 @12:51AM (#4996833)
      If you are serious about doing synthetic work, I
      would see about taking several lab courses at a
      local college. They are already set up with
      sources for the reagents, safty equipment (ie,
      hoods, glove boxes, safe storage for the reagents,
      safe disposal of the reagents, plus more
      analytical instrumentation so that you will be
      able to confirm that what you made is what you
      intended to make.

      If you really insist on seting up a lab at home,
      make sure that you set up a safe lab. Please do
      the following:

      1) Ensure that you can safely store, handle and dispose of any reagents.
      2)Be sure to join an amateur scientist oganization, and find some help, if only to double check that you are doing #1 correctly.
      3) consider the legal difficulties
      -in the state of texas it is a felony to own
      certain common glassware without a permit.

      Just to be safe, check your local laws along
      with the fire codes.

      4) If you can legally own glassware, consider
      buying the microscale equipment. It should
      be the same price or less for it, however
      you'll use smaller volumn of reagent.

  • by black_widow ( 41044 ) on Wednesday January 01, 2003 @11:53PM (#4996615) Homepage
    Personally, I never learned any practical info in chemistry labs... Come to think of it, high school chemistry is all you're ever going to need unless you're going to be a chem engineer.

    • I didn't learn too much in the required labs, but spending a semester or a summer in a lab doing research you will learn more than any number of classes or books you read.
    • Well, at the rarefied heights of "chef" and "pastry chef" there is generally a pretty good working knowledge of a limited subset of organic chemistry as it relates to food and taste. And sometimes a pretty impressive set of knowledge -- find a good pastry chef and ask them about the chemical interactions involved in a loaf of bread...and be ready for a 2 hour long lecture.

      A guy I worked with once told me "if you're cutting up a steak for people to sample, don't cut it into little cubes...cut it into long, thin strips...it tastes better because it provides a greater surface area for {big long enzyme in the saliva} to work with". (He then told me, "I learned that in the Organic-Chemistry-for-Chefs Class that I took last year". (And, yes, he really used the phrase "organic chemistry".)). Of course, I immediately put this to a field test with about 5 people (including myself) as test subjects. Sure enough, he was correct...the same steak -- when cut into long thin strips -- tastes better than the when it's cut into an volumetrically equivalent cube.

  • by Quaoar ( 614366 ) on Wednesday January 01, 2003 @11:55PM (#4996630)
    I think it's about time we added a "hydroponics" category. Honestly, most nerds will probably applaud it.
  • by Cybersonic ( 7113 ) <ralph@ralph.cx> on Wednesday January 01, 2003 @11:57PM (#4996635) Homepage
    She saw me reading the Radio Shack 'Getting Started In Electronic's book over and over again and (in between studies for various certifications) and decided to get me a kit.

    She gave me bookmarks after chrismas... :)

    Good list of kits: http://www.hobbytron.net/electronickits.html [hobbytron.net]

    I have the 300-on-1 which is $70 and is solderless.

    Also check out http://www.kitguy.com/ [kitguy.com] - seems to be a definitive resource...
  • by oliverthered ( 187439 ) <oliverthered@hotmail. c o m> on Wednesday January 01, 2003 @11:58PM (#4996639) Journal
    Well, if you wan't to have lots of fun, well kinda, try making some of the chemicals you self or using household goods.

    Amonia isn't that hard to make,
    Ethanol's quite easy too (just don't get caught!)
    Acids are a bit trickier.... but not that hard.

    It'll give you lots of practice nad help if WW3 breaks out(or if you need any 'added-extras' for a night out).

    Things like the anarchists cook book [come.to] should help point you in the right direction.
    • by driftingwalrus ( 203255 ) on Thursday January 02, 2003 @12:03AM (#4996667) Homepage
      ACK!!! Great stars! Are you *MAD*?! NEVER take anything from the Anarchist's Cookbook. Might as well drink a jug of chlorine, it'll do the exact same thing and save you a lot of time.

      • He's right, some of the recipes in the Anarchist's Cookbook have been doctored so as to cause the "chemist" injury.
        There are more reputable texts out there to learn from.
      • by Thatmushroom ( 447396 ) <Thatmushroom@@@mille352@@@purdue...edu> on Thursday January 02, 2003 @12:37AM (#4996802) Homepage
        To clarify, there are multiple versions of the Anarchist Cookbook, and if that's a copy of the original, just strap some TNT to yourself and light it, it really will save you time in the long run. The original is replete with errors, many chemical, that could cause lots of damage.

        However, I doubt that's the original, since the original is extremely rare (if you don't see something about the bridges in NYC, you're not looking at the original). Still, it's not a wise move to perform chemical experiments using instructions from a book that's designed to cause destruction, chaos, and anarchy.

        If you're really just looking to win a Darwin award, however...
      • Nitrogen triiodide (Score:4, Informative)

        by MillionthMonkey ( 240664 ) on Thursday January 02, 2003 @07:33AM (#4997651)
        Agreed. If you've never seen the Anarchist's Cookbook, it's rather like a long "Overrated" Slashdot post printed on paper with pictures and a handsome black cover. The guy doesn't really understand most of the things he discusses and is on the firmest ground when he sticks with safe topics (guns and knives). It was written during the Vietnam era by a pissed-off draft age guy. Now he's turned to Jesus and says he wishes he hadn't written the book at all. Another mind lost to religion.

        The best explosive recipe in the book is one that the author discounts in passing- nitrogen triiodide [bris.ac.uk], or NI3. (Actually, the structure is NI3-NH3, where the NH3 is bound to the NI3 electrostatically by what resemble hydrogen bonds.) According to the Cookbook a fly landing on it will set it off (which is probably true, although I never succeeded in getting a fly to cooperate). It claims it's too useless for any serious consideration when planning your anarchy. It might not be good for that, but it's great for pranks. [armory.com] I've had so much fun with that stuff. The secret to NI3 is DO NOT MAKE TOO MUCH OF IT. That way you can keep your fingers. [wisc.edu] A gram is way too much. Just take a few iodine crystals and put them under ammonia, and presto, it turns into this black powder. If you keep it under the ammonia, it's actually quite stable. When not under ammonia (even when under pure water) it might go off at any moment. Pick it up from the ammonia with a plastic eyedropper, and deposit the black sludge on some surface. Once dry it rapidly loses its NH3 adduct and becomes extremely sensitive to shock, decomposing explosively producing N2 and I2. Don't get traces of it on your clothes or skin, or you'll be treated to a continuous snap-crackle-pop of microscopic explosions (quite annoying).

        Finding references on it is difficult- it's almost like people don't want to do research on it. It's probably unstable because the iodine atoms are huge compared to the nitrogen. Congestion around the central N forces the molecule into a planar shape, with repulsive interactions among the three iodines, so it's unhappy for steric reasons. One thing I did find out was that the stuff turns bright orange if you leave it under the ammonia for a long time (like a month). This is probably because it picks up additional NH3 adducts.

    • "Ammonia isn't that hard to make"

      If you are so good with high pressure process plant, building catalyst beds, pumping hot nitrogen and so forth, that ammonia isn't hard to make, you hardly need a Chemistry 101 kit.

      Of course, if you just mean "extract from something that already contains it", that's a piece of cat's piss. Literally.

  • sugestion (Score:4, Funny)

    by larry bagina ( 561269 ) on Wednesday January 01, 2003 @11:58PM (#4996641) Journal
    ask your local meth lab if you can do some intern work.
  • My All-time favorite (Score:5, Informative)

    by Superfreaker ( 581067 ) on Wednesday January 01, 2003 @11:59PM (#4996645) Homepage Journal
    Edmund Scientific
    http://www.scientificsonline.com

    My dad used to take me there when I was a kid, a very trippy place. It got me through all of my science classes with pre-made projects.
    • by jayed_99 ( 267003 ) on Thursday January 02, 2003 @02:03AM (#4997017)
      Some of my favorite childhood memories are negotiating with my father about what I could select as a Christmas/birthday gift from the Edmund's catalog.

      Me: "I want one of those ruby-laser kits."
      Him: "No. What about a prism?"
      Me: "I want one of those sets that has all the chemicals."
      Him: "No. What about a prism?"
      Me: "I want one of those magnets that can lift a small car."
      Him: "No. What about a prism?"

      I got a *lot* of prisms. By the time I was eight, I had about a dozen of varied shapes and sizes.

  • alright (Score:3, Funny)

    by pummer ( 637413 ) <spam AT pumm DOT org> on Thursday January 02, 2003 @12:01AM (#4996654) Homepage Journal
    first, you buy a textbook, like the one you had in 11th grade. Then, you place it under your pillow and learn by osmosis.

    or

    you take a big ol' jar of gasoline, add styrofoam until you get a play-doh like mixture. what you have is napa----------

    oops, you were asking for suggestions. I thought you wanted to know what I did.
  • by pi_rules ( 123171 ) on Thursday January 02, 2003 @12:01AM (#4996656)
    It's actually a little bit of biology mixed in with a bit of chemistry; but it's really fun to play with.

    It's a home-brew kit for making my own beer :) I could entertain myself for hours with this thing.

  • by Walt Dismal ( 534799 ) on Thursday January 02, 2003 @12:02AM (#4996662)
    Modern chemistry sets are crap; they have been gutted because of fear of lawsuits. So the materials and the experiments are bland and useless unless you're 8 years old.
  • Blow Stuff Up! (Score:2, Interesting)

    It's obvious why this guy wants a chemistry set... The same reason we all wanted one:

    To blow things up.

    There is a solution, though.

    A hand full of sodium + a large lake = very nice explosions.

    You can learn the importance of keeping alkaline metals away from water, the amount of energy created with the mixing of H2Oand sodium, and why you should never stick sodium in someone's bathing suit.

    Can you say, "Win Win."
    • BTW, raw sodium is pretty dangerous to handle. The same properties of sodium that cause great loads of fun with lakes can cause some not-so-fun effects with the moisture on your skin (or in the air).
    • Exactly ;P

      I was toying with the old "blowing stuff up" bit when I was in highschool. Decided to whip up a batch of ammonium nitrogen triiodide in the basement.

      I managed to procure some pure iodine crystals from a drugstore (I still don't know why (a) they had them, or (b) why they sold them to me).

      Unfortunately my ammonia wasn't strong enough to react particularly well, but it was good enough that I got the reaction going a bit - I left it in the sink tub and went off to watch TV for a bit - while I was gone, everything dried out...

      When I was going back into the room, I flipped the lights on and heard something between a pop and a bang. It's amazing how unstable that stuff is - certainly not good to play around with...

      Turns out that if I had borrowed some ammonia from my friend's blueprinting machine, I probably would've got a much better reaction (it was enough to knock him out cold when he decided to smell the ammonia).

      To add to the problems, the iodine crystals slowly sublimed over a few weeks while in the container on my shelf, turning the container a nasty red/purple color, and probably didn't do me much good as I inhaled the stuff...

      N.
  • by (H)elix1 ( 231155 ) <slashdot.helix@nOSPaM.gmail.com> on Thursday January 02, 2003 @12:06AM (#4996679) Homepage Journal
    I'd be real careful about buying 'chemistry' kits these days. If the war on drugs does not send the suits to your door, I'm sure the war on terror will.

    Brewing - wine and beer are a good start. A fair amount of chemistry (and biology) involved when you think about it. Taking the alcohol content above 15% or so lets you play with even more toys.

    Best college experience was making moonshine from captain crunch in the dorms. A bit of enzymes to convert the starch to sugar, let bubble, then we pulled out the still. Nothing like a mass spectrometer to assure you don't go blind....
    • You will have a difficult time buying reagent chemicals too ! Most supply houses will not sell to private individuals.

  • by oldzoot ( 60984 ) <morton.james@co m c a st.net> on Thursday January 02, 2003 @12:06AM (#4996680)

    The experimenters labs are good for starting out - having a structured set of experiments to build, and yes, you can even go beyond those simple experiments and build simple experiments which are not in the book. For the most fun, however, I like the prototype breadboards. One of those with appropriate power supplies and other test equipment is good for analog, digital or combination circuitry. Add a few experimenters parts kits from Jameco and you are in business.


    As for Chemistry kits, I think just buying the labware you need and the various chemicals etc. is a better way to go than a pre-fabricated kit.


    The real interesting stuff however would be a molecular biology lab. Slice and splice DNA and build your very own new and interesting critter! Yes, you too can build your own miltary grade anthrax, plague or even smallpox. Add the THC gene to corn! Create that perfect paisley rose! Be the envy of everyone on your block! hmmmm I better quit now. Seriously, it is probably not all that hard to build a DNA synthesizer. Why not convert an ink-jet printer ? DNA = 4 molecules, many printers have 4 ink tanks. How tiny of a drop can you print???



    Z
  • As a Chemist.... (Score:5, Insightful)

    by BadlandZ ( 1725 ) on Thursday January 02, 2003 @12:07AM (#4996682) Journal
    You asked for recommendations, so here's mine. As a chemist, I recommend not getting one at all. There is nothing that fun in a chemistry set anymore (for legal reasons, almost everything fun is dangerous, so not in any set). You'll probably find more stuff in your own kitchen cabinet now days anyway if you know what your looking for.

    I would recommend a molecular model kit though if you really want something to play with, or if you want to be more geeky, you can get some molecular modeling software.

    • Working with *real* reagents one can learn that in the real world reactions don't have 100% yield, real reagents have impurities, improper techniques can lead to erroneous results......I think that playing with sticks & balls or modelling electron clouds on a PC is fine, but it's only one very tiny part of chemistry.

      Take the first quarter or semester of general chemistry at a local two year community college...if you like it, then finish the general coursework, then figure out if you next want to take physical, organic, inorganic......
    • I thought about working through the kitchen cabinet. My only worry is, "What about all that other stuff they put in there?" Bleach isn't just Sodium Hypochlorite (or whatever it's supposed to be- it's been ages), it also has a bunch of other stuff in it. I always worry about the unknown additions reacting with other unknown additions and making something terribly wrong.
      • by BadlandZ ( 1725 )
        You actually have a lot to worry about with "pure" chemicals also. I wouldn't recommend doing anything without having a fire extinguisher, goggles, a lab coat (or something that can easily be ripped off of you if you spill something on yourself) and an eyewash and fume hood.

        I suppose being outdoors would substitute for the lack of a fume hood, and a garden hose would be ok for eyewash. However, your never suppose to work alone in a lab, because if something goes wrong you don't have anyone to help you. How do you find your way to an eye wash when you can't see?

        A freshman lab manual from any college bookstore will give you an idea what some simple experiments are, and what you learn from them. Reading through one would be a good place to start to figure out what you would want to try. But, it's still best if your assisted somehow. And I won't recommend anything to do on your own...

        There are some people who need to actually see something happen in order to believe it's true or let it sink in, and that's where lab work really helps learning. But, the number of people I've seen cut themselves, spill stuff, or start accidental fires pretty much tells me, it's best to do in a lab, with an instructor. At least the instructor knows the risk of each experiment, and knows what to do when things go wrong.

        The goal of chemistry lab classes is more to teach good lab techniques and lab safety. Learning chemistry in the lab is only a secondary benefit, most of the learning actually comes from books and lectures. It's the physical skills of handling materials that's learned in lab, and without instruction there isn't much learning you can do on these skills on your own.

  • I can see the FBI looking very hard at any adult ordering his own chemistry set.

    something to strike fear in their hearts in any number of areas.

    you can imagine the conversations.

  • Do it piecemeal (Score:3, Informative)

    by elnerdoricardo ( 637672 ) on Thursday January 02, 2003 @12:09AM (#4996692)
    Here's an idea.... Here in Toronto we have a great store downtown called Active Surplus. You can buy just about anything there. They have a pretty good glassware section where you can get most of the things you need... stopcocks (*snicker), flasks, beakers, pipettes, etc. I would think that most major metro areas have a similar store. Great place to get all the glassware you'd need. I would think another great source of info and leads would be the local highschool. Go in some day and have a chat with the Chem Teacher. I would think they'd have catalogues and suggestions for what you should have to get started!
  • Forget the chem set (Score:2, Interesting)

    by grub ( 11606 )

    and thought it would be fun to acquire a chemistry set just to play around with and maybe learn a few things from

    If you want an adult-style chemistry set, try one of those home beer brew kits or a home winemaking kit. You get to monkey around with various ingredients and after its all done you reap the rewards. err.. "Reap Responsibly"..
  • SODIUM !
  • I havn't seen serious chemistry sets in years, i figured they stopped making them cuzza people like me, same with real lawn darts.
  • My childhood garage probably still has purple and black stains all over it

    Usually those stains [everything2.com] are kind of yellowish. What the hell are you?
  • I would definitely recommend the Anarchist's Cookbook. Full of fun stuff, ie thermite and other stuff I can't remember. Just don't get caught with it, though. If you do, I never posted this (uh, well, you know what I mean :)
    • ask any chemist you know about the anarchist's cookbook, or show them if they don't know it - 40% of the stuff in it doesn't work, 40% will blow up yourself, 15% are urban legends, and the rest may work if you do it right.. if you are interested, get some real books, like "Explosives" by Rudolf Meyer...

      be warned however, creating explosives, or drugs for that matter, is nothing a chemistry kit could archieve most of the time.. the only synthetic drug I am aware of that could be made this way would be GHB, which can be easily produced by mixing two chemicals, then heating them carefully. As for explosives.. creating things that go boom without the exact knowledge of what you do often result in the quick and impressive end of the creator's life. :)

    • There are various versions of the Cookbook circulating in print and on the web; some contain gross inaccuracies, some have been corrected--partially. Consult a chemist, or a real textbook, before you try anything.

      Well equipped university libraries should have books on the chemistry of fireworks--they're not a bad source of ideas. Information on explosives can be found at schools with good chem. eng. or mining programs.

      Be very careful with organic synthesis of any kind, in any quantity. Plan ahead--have a fire extinguisher on hand, and work where there is good ventilation. Don't work where nobody will hear you scream. A litre of solvent triggered with a blasting cap will throw shards of glass a couple hundred feet, except for the bits that are slowed down by your body. Less spectacular errors can be just as fatal. Consider yourself warned.

  • Those 300-in-one sets frequently encouraged you to experiment by modifying the circuits...let me tell you, replacing the components when they burned up wasn't exactly the most fun thing to do, particularly when you couldn't readily determine which ones aren't working the way they're supposed to. I suppose an experienced engineer could readily do that, but a 12 year old kid trying to learn?

    Sure was fun to have my own 10mw-ish AM station, though.

    Frankly if I were to do it all over again I'd just go buy a bunch of components, a soldering iron and a few prototyping boards. They still make those prototyping boards, don't they?

    • Frankly if I were to do it all over again I'd just go buy a bunch of components, a soldering iron and a few prototyping boards. They still make those prototyping boards, don't they?

      I'm sitting right beside a 300 in 1 kit (or, from where I'm looking at it, "300 in 1 elektronische projektdoos"). Prototyping boards are great, definitely more flexible. They have spring-loaded ones with horizontal and vertical tracks so you just "plug in" your components. No soldering needed. I've been using these a lot!

      I had a flashback to my first crystal set radio. I ran a big wire (antenna) to a tree to pick up strong signals. Then the radio works without any battery. How can anyone say that's not neat!

      If you have some time to kill, go build one [google.com]!

  • environment, geology (Score:4, Interesting)

    by g4dget ( 579145 ) on Thursday January 02, 2003 @12:56AM (#4996842)
    Measuring and monitoring the presence and amounts of chemicals in the environment and in food might be a good area to get involved in. You can get by with limited resources, the experiments tend not to be dangerous, it teaches excellent laboratory technique, and you can accomplish something useful. You could pick a problem that interests you personally (oxygen levels, organic matter, pollutants in a local lake), or you might look around for a volunteer organization to get involved in--they might even be able to provide laboratory facilities and train you.

    Other areas that involve chemistry and makes a good hobby are geology and mineralogy. You can collect samples, characterize them, learn about crystallography, and also analyze the samples chemically.

    And if you get seriously involved, you can actually accomplish new science in areas like those, even with fairly modest resources. There are lots of publications dedicated to both the hobbyist and the professionals in those areas; look at them at your local university library to get some ideas.

  • by Avionics Guy ( 635626 ) on Thursday January 02, 2003 @01:03AM (#4996862) Homepage
    By all means, check out the Student Science Service (http://www.tri-esssciences.com) in Burbank, California. They sell a few high-end chemistry sets of their own design (these are not kiddie sets). Ira Katz and his daughter, Kim, are the owners and are easilly accessable via e-mail. They're also one of the largest suppliers of pyrotechnic special effects to the local movie studios. Can't recommend 'em enough. -Kevin
  • If you get a chemistry set, expect intrusions from nosy and thuggish bastards in ninja suits, who are operating on the assumption that you are making drugs, of which for some daft reason they disapprove.
  • sciplus (Score:4, Interesting)

    by beej ( 82035 ) on Thursday January 02, 2003 @02:13AM (#4997046) Homepage Journal
    Cheap beakers and things, as well as a variety of cheap cool geekstuffs: http://www.sciplus.com/ [sciplus.com]

    Warning: prepare to spend at least an hour looking at this site.

  • by sakusha ( 441986 ) on Thursday January 02, 2003 @02:45AM (#4997149)
    Get into developing and printing your own photos. You know, the old analog kind. Even better, study some old antique photo processes like Cyanotype or Platinography. I make my own photo papers using these antique methods, and it is satisfying enough to keep me interested, and I was an Honors Chem major until I switched to art, majoring in photography).
    Making your own printing papers and photochems is a ton of fun, and yields tangible results (unlike most things you could do with a chemistry set).
  • by jms ( 11418 ) on Thursday January 02, 2003 @02:53AM (#4997166)
    One of the most interesting and rewarding reactions you can study as an amateur is mirror silvering using Tollens' reagent. I had an arc lamp reflector that needed resilvering, and decided to do it myself.

    After a lot of web research, I found that this website had the best directions (and the best safety warnings!):

    http://lerch.no-ip.com/atm/Silver.htm

    The only chemicals I had any trouble finding were silver nitrate crystals, which can be purchased from photography supply stores, such as:

    http://www.photoformulary.com/

    or ebay, and concentrated nitric acid, which can be purchased from lithography supply stores, such as:

    http://www.rembrandtgraphicarts.com/13_rga_cat.h tm l

    The hazmat shipping charge for the nitric acid will exceed the cost of the chemical.

    The process is somewhat complex, involves a number of stages, but isn't too difficult to do. It's an interesting reaction to watch, and the result is cool and useful. I created a perfect mirror coating on the inside of a bottle on the second try, and successfully coated my reflector mirror immediately thereafter.

    Everything worked for me, except that I found that I had to heat the muriatic acid in order to make the solder dissolve when creating the sensitizing solution.

    That's my recommended interesting experiment.

    • This reminds me of something else you can do for fun, with chemistry.

      Develop your own photographs [about.com] (fun, but not tedious enough). Better yet, create your own PCBs [telia.com] (fun, and very tedious). As with the mirrors, you end up with something worthwhile when you're done.

      If you're just looking for some pointless fun, drop round pennies in Tinning solution. See how many people you can trick into thinking it's a nickel.
  • I've got one. Mine has extasy, lube, body oil, edible paint, and all kinds of stuff that adults like to play with.
  • Who needs it? (Score:4, Informative)

    by Tuxinatorium ( 463682 ) on Thursday January 02, 2003 @03:36AM (#4997259) Homepage
    You can get all the chemicals you need at hardware stores, etc.

    Examples: ammonia (cleaning), potassium nitrate (fertilizer), calcium cloride (road salt), ammonium nitrate (fertilizer), various petroleum distillates (everything), all sorts of metals, various exotic metal oxides (dry paint powders and ceramic glazes), sodium hypoclorite (bleach), hydrofluoric acid (for glass etching), hydrochloric acid, calcium sulfate (gypsum), etc... you can get almost any chemical you need for any purpose from common products, or manufacture it from common products. You just have to know what you're doing.
    • Re:Who needs it? (Score:5, Informative)

      by Graff ( 532189 ) on Thursday January 02, 2003 @09:51AM (#4998032)
      IAAC (I am a chemist)

      You can get all the chemicals you need at hardware stores, etc.

      I totally agree with this. Most "modern" chemistry sets are so sickeningly-safe that they do not truly allow any chemistry to be done. I would collect your own chemicals, maybe buying a chemistry set to give you some guidance.

      There are several cautions that I would keep in mind. First of all, chemistry is highly dangerous. Many of the "first" discoverers of a chemical compound of process have actually turned out to be the second, third, etc. The true first discoverers literally killed themselves in the attempt and were thus not able to make their claim to fame! The first inventor of gunpowder, the first discoverer of fluorine, chemistry is riddled with those that tried something without understanding the consequences of their actions.

      Get several good chemistry texts and read them all the way through. Start off with simple, harmless experiments. Do not try anything potentially explosive, corrosive, or vapor-producing. Keep several neutralizing agents on hand, such as baking soda, lime, sand, a good multi-purpose fire extinguisher. Perform your experiments in an extremely well-ventilated area that has been fireproofed and is far away from any living or eating areas. A separate shack is a good place. Use goggles, a heavy rubberized and/or canvas smock, solid leather shoes, disposable gloves and face masks for some experiments.

      Never leave an experiment unattended. Never dump the results of your experiments in the same place, they can sometimes cross-react and form a dangerous mixture. Do not store anything which has the potential to become unstable, many nitrogen and phosphorous compounds can spontaneously react and cause extreme heat, vapors, or explosions.

      Make sure of the purity of your ingredients. If you get ordinary bleach for the sodium hypoclorite be careful - perfumes, surfactants, and other agents are often added to them which can cause unwanted reactions to occur. The same goes for household ammonia cleaning solutions. Most metals you will get will be alloys, always understand the elements in the alloy and how they may react in an experiment.

      Yeah, it's a lot to keep in mind, but chemistry is truly a dangerous business. I've been working in chemical labs for over 10 years and I've seen professional chemists with doctorates have accidents that you wouldn't believe. Explosions, runaway reactions, improperly ventilated experiments, splashes of highly corrosive compounds, forgetting to turn on or off some crucial bit of equipment, a lot of people get hurt even in the safest laboratory. I'm very careful simply because every exposure to some of these chemicals shortens my life-span. Many of the chemicals will take up permanent residence in your bones, will leave holes in your liver, will cause you to go blind, or even will make you go sterile. Lots of them have a cumulative effect so every exposure increases the risk, no matter how much time has passed.

      So be careful!
  • Alfa Aesar (Score:4, Informative)

    by Galahad2 ( 517736 ) on Thursday January 02, 2003 @03:53AM (#4997298) Homepage
    Alfa Aesar [alfa.com] sells chemicals en masse. They'll even send you a catalog for free. I'm not sure, but you probably have to have a license to buy anything from them.
  • by MickLinux ( 579158 ) on Thursday January 02, 2003 @04:21AM (#4997351) Journal
    You of course will need chemicals and chemistry equipment. I expect that you could call the local high school and find out where to get them -- and the high school teacher could suggest where you might get a nice sampling. I can't help a lot there.

    But perhaps I could suggest a book, instead:

    Laboratory Experiments for General Chemistry, 4ed
    by Hunt, Block, and McKelvy
    http://www.amazon.com/exec/obidos/tg/deta il/-/0030 32906X/qid=1041495102/sr=1-1/ref=sr_1_1/103-128032 3-3723057?v=glance&s=books

    This one is extremely useful in that it:

    (1) Lists the equipment needed for each (so you can go through, find the experiments that you can do)
    (2) Lists tons of safety and first-aid information, with standardized icons for each item
    (3) provides lab reports to fill out, which will help you understand the experiments
    (4) The experiments are actually rather standard; not all of them require special equipment.

    One word of caution: After produced the book, my brother noted that one of the experiments, standard to most College Chemistry Lab courses, is wrong:

    Experiment 13, the Burning of a Candle.

    My brother claims that the experiment purports to demonstrate the stoichiometry of combustion; in reality, it demonstrates the heat given off by candles, and the ideal gas law PV=NRT. He said that he demonstrated this by attempting the experiment in several different ways, one with 3 candles close together (burning hotter), one with three candles farther apart (burning cooler).

    I haven't done that experiment myself in his way. But I thought I should mention that.

  • Just some advice from CmdrTaco's web site. [cmdrtaco.net] (it's one of his cartoons.)
  • The only way to get a "chemistry set" that doesn't have plastic beakers and anything more fun than baking soda and vinegar is to get an old one made in the 50's or 60's. My old roommate found lots of good stuff on Ebay.

    Another good source of chemicals are some of the fertilizers you can get at a local nursery. If you have a good local nursery you can find things like ammonium nitrate, phosphoric acid, sulfur, etc. Professional growers often need to mix specific fertilizer "recipes" with these ingredients, which happen to have lots of other uses besides growing plants.

  • You need ammonium hydroxide (amonia cleaner from the store) and iodine crystals (used for swimming pools, and cleaning horses, but also for making meth, so sometimes hard to get). Put the iodine in a coffee filter and pour ammonium all over it for a while. When it dries you get ammonium triiodide. Highly unstable, keep in separate small amounts, don't look at it funny.

    Ahh home chemistry is great
    • Keep it wet, and it doesn't go boom. :) I had a rackful of this stuff drying in the back of a chemistry class when I was a chem aid. Needless to say, I heard it down the hall (in english class) when the next period's chem aid set it off when moving the rack (which to my credit was marked "Contact explosive, do not touch"
  • by tres3 ( 594716 ) on Thursday January 02, 2003 @08:22AM (#4997753) Homepage
    I'm especially surprised that you can purchase concentrated nitric acid online. Since everyone else is pitching their favorite receipies here's my simple recipie: Take toluene (aka Boat Cleaner - a benzene ring with a methyl group stuck to it) add sulfuric acid (The liquid from your car battery) and slowly add the nitric acid that I didn't know you could buy without some sort of permit. I always thought that you had to convert sulfuric acid to nitric acid with amonia and some complex chemistry. The oily stuff that forms on top is what you are looking for -- ortho-ortho-para-nitrated toluene a/k/a tri-nitro-toluene a/k/a TNT. Everybody remembers their bombs and drugs from Organic Chemistry right! DO NOT DO THIS I have left out a number of steps like fixing the pH in the final product and the correct temperature to make it. If you do not know the missing steps and just try your luck IT WILL BLOW UP IN YOUR FACE.

    If you wants to get really crazy/stupid start with phenol instead of toluene and you will end up with picric acid. Opposites attrack and like things repel and this has more negatively charged things around the benzene ring and is thus much less stable -- especially when it dries! Once again, DO NOT TRY THIS AT HOME without proper adult supervision (and that means someone preferably with a chemistry degree).

    And the feds wonder where people learn this shit!

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