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Microbes Churn Out Hydrogen at Record Rate

Posted by ScuttleMonkey on Tue Nov 13, 2007 06:41 PM
from the now-make-stuff-that-uses-hydrogen dept.
FiReaNGeL writes to mention that Penn State Researchers have improved on their original microbial electrolysis cell design bringing the resulting system up to better than 80 percent efficiency when considering all energy inputs and outputs. "By tweaking their design, improving conditions for the bacteria, and adding a small jolt of electricity, they increased the hydrogen yield to a new record for this type of system. 'We achieved the highest hydrogen yields ever obtained with this approach from different sources of organic matter, such as yields of 91 percent using vinegar (acetic acid) and 68 percent using cellulose,' said Logan. In certain configurations, nearly all of the hydrogen contained in the molecules of source material converted to usable hydrogen gas, an efficiency that could eventually open the door to bacterial hydrogen production on a larger scale."
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[+] Scientists Use Microbes to Produce Hydrogen 190 comments
An anonymous reader writes " Environmental engineers at Penn State University and a research scientist at Ion Power Inc. have created an electrically-assisted microbial fuel cell that can be used to produce hydrogen from organic material. The amount of electricity needed for the process is less than the amount required to power a standard cell phone. This advancement can be used to produce hydrogen as a byproduct of water treatment. " Coverage at ScienceDaily as well.
[+] Hardware: New Solar Cell Harvests Hydrogen From Water 222 comments
Engadgets is reporting that researchers at Penn State have built a new kind of solar cell that can harvest hydrogen directly from water. "The folks at Penn State have now developed a process that more closely mimics the photosynthesis process in plants, and while we won't pretend to understand all the nitty gritty of dye usage and other such nonsense, we do know that such a system could eventually attain 15% or so efficiency, providing a nice and clean way to gather power for that fuel cell car of the future."
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  • by LiquidCoooled (634315) on Tuesday November 13 2007, @06:42PM (#21342807) Homepage Journal
    Quick, block and ban this article before the boss sees it.
    If he had his way he will fill the water cooler with vinegar to try to increase our productivity.
    (If you are working at EA I'm afraid its too late)
  • Uhm (Score:3, Interesting)

    by lorenzino (1130749) on Tuesday November 13 2007, @06:43PM (#21342819)
    This reminds me a lot of some Asimov books. So, are we getting there ?
      • Re:Uhm (Score:5, Informative)

        by Rei (128717) on Tuesday November 13 2007, @07:29PM (#21343321) Homepage
        Hydrogen beats the crap out of batteries as far as energy storage

        Not currently it doesn't. Top-of-the-line hydrogen-powered vehicles are about on par, range-wise, with top-of-the-line lithium-ion powered vehicles (for vehicles released this fall, say, compare a Roadster with an Equinox -- both 200 mile range). But they're notably less thermodynamically efficient and have worse performance. Honda has a prototype FCX that they say will be able to get 350 miles by using an undisclosed storage material, but storage materials always raise issues of their own (such as how much energy it takes to get the hydrogen in and out -- thus hurting the thermodynamic efficiency even more), and if you want to count vehicles that don't exist yet... Of course, if your energy source is hydrogen *to begin with*, sure, hydrogen would be a better choice present-day. We'll have to see how each respective technology advances. Personally, I'd rather we be driving largely on grid power instead of trying to store all our energy on the vehicle ;)

        Getting this sort of tech as a backyard/rooftop energy generator could be insanely useful

        You want them to eat your roof? You did read the article (or even the summary) and realize that these aren't photosynthetic bacteria, right? That will almost certainly come in the future, but that's not what we're dealing with here.

        A biological system would (probably) be lower setup than a solar system as well, at least given current tech.

        But maintenance can be very tricky. Bacteria mutate, get attacked, and so on. Plus, you need to keep feeding them and removing waste products. This is certainly viable, present-day, in industrial scale applications, but it probably won't scale down very well any time soon.

        I will agree with you on one thing:

        Wow. And 80% efficiency is pretty damn good, for a line of research that is still pretty primitive.

        It sure is.
        • Re: (Score:3, Insightful)

          Keep in mind that septic tanks work on this principle, just drop new tablets of the bacteria in every once in a while and processing resumes, clear water leeches out and there is a ready supply of food for them. Been in use on small scale for a very long time. Composting also works with a constant supply of food on a small scale.

          As for eating your roof, there are already bacteria that do that, but they have to be in the belly of a termite to survive, likewise if some of these were to get out, I don't imagin
        • Re:Uhm (Score:5, Insightful)

          by 2ms (232331) on Wednesday November 14 2007, @12:16AM (#21345857)
          Why are you comparing batteries to fuel cells in "thermodynamic efficiency". Batteries do not have "thermodynamic efficiency". A battery is not an engine, it's a container of an electrical potential that was put there probably by burning coal. You do realize that's where something like 80% of grid power comes from right? The battery's analog in current automotive propulsion is the gas tank in your Honda or whatever. Find out what the "thermodynamic efficiency" of the process of creating the electricity and then getting it into your lithium ion batteries, and then we can start making useful comparisons to other systems for automotive propulsion. Also, talking about range as if the range of a fuel cell vehicle was directly comparable to the range of a simple/straight EV (ie no production of power on bard, only storage) has limited validity too -- hydrogen vehicles are able to refill their hydrogen tanks about as fast as current gas cars fill their's, if not faster. EV's on the other hand, need to sit at a charger for a minimum of a couple hours, and if battery longevity is desired, really need to charge over an entire night. By the way, for those of you who don't know about it the Fuel Cell Equinox [autoweek.com] is extremely impressive. It's a mass produced, production fuel cell vehicle with the full interior room of a normal Equinox, that'll be driven by 1000 "owners" in the 3 major cities next year. It's been quite a wakeup call to the rest of the auto industry.
          • Re: (Score:3, Insightful)

            although depending on their metabolism they may see the production of hydrogen as inefficient way of reproducing themselves and switch to a different by-product that works faster

            That's indeed part of the problem from what I've heard for using bacteria to produce stuff.

            Likely any home user would have to 'scrub' his system every so often as non-hydrogen producing bacteria start emerging and taking over. Hopefully the fix would be equivalent as opening a yeast packet for making bread is today.

            Still, I don't s
  • by eln (21727) on Tuesday November 13 2007, @06:46PM (#21342849) Homepage
    This is absolutely horrible, and I demand it be stopped! These researchers are advocating the mass enslavement of innocent microbes. These microbes will be forced to work nonstop on Hydrogen production from the moment they are born to the moment they are finally literally worked to death. Multiple generations of microbes will toil endlessly in these bacterial concentration camps, with no relief in sight!

    We must stop the senseless abuse of microbial rights! We must fight for the smallest and most vulnerable among us! Stop this horror now!
    • by Jeremi (14640) on Tuesday November 13 2007, @06:58PM (#21342977) Homepage
      These microbes will be forced to work nonstop on Hydrogen production from the moment they are born to the moment they are finally literally worked to death


      Relax, dude. We've fixed them up with an excellent simulation of their society at the peak of its development. They'll go happily about their simulated lives, and never know they are just sitting in a vat generating power for us.

  • by Penguinshit (591885) on Tuesday November 13 2007, @06:48PM (#21342873) Homepage Journal

    I have a high hydrocarbon yield from beer. Does that help?

    Cabbage consumption increases yield dramatically!

  • From the PSU Press Release [psu.edu]:

    "This process produces 288 percent more energy in hydrogen than the electrical energy that is added to the process," says Logan.

    That illustrates just how big the jump in efficiency is here. These bacteria are amazing little energy multipliers. It's quite astonishing!
  • by compumike (454538) on Tuesday November 13 2007, @06:58PM (#21342981) Homepage
    The 80% figure is impressive. But beware of the efficiency numbers they quote. This isn't the full fuel cycle. You've still got to compress and distribute hydrogen, which takes a lot (gases take lots of work to compress). For a vehicle, burning it isn't too efficient maybe 30-40%, and fuel cells aren't quite there yet.

    Additionally, with any kind of electrolytically-driven process like this one, there's a HUGE efficiency penalty once you increase the flow rates to be anything substantial. And you need to, because otherwise the amount of hydrogen produced per fuel cell area would be tiny. And then, at that point, you've got the problem of lots of carbon to dispose of. Guess what -- this working microbial fuel cell takes C,H,O in as vinegar or cellulose, and outputs H2 and CO2! Do you really call that 'carbon neutral' as a fuel source? It's still dumping CO2 into the atmosphere, just less of it per Joule of useful energy.

    Still, this is a great direction for them to keep going... there are very interesting things you can do with hydrogen, even to extend existing liquid fuel stocks (i.e. crude oil to gasoline) by hydrogenation. (Much cheaper than building lots of fuel cells... but not carbon-neutral.)

    --
    Educational microcontroller kits for the digital generation. [nerdkits.com]
      • Re: (Score:3, Insightful)

        Yes, I do call it carbon neutral. The plants take in CO2, H2O and E to create vinegar and cellulose, and due to thermodynamics, plants can't create more H2O and CO2 than they take in; so by definition it's carbon neutral.

        Except that CO2 is now airborne again instead of locked inside the plants, when they could have carried it deep into the soil and become fossil fuels.

        By your logic, the planet as a whole is carbon neutral as nothing from the outside is adding carbon. Indeed, putting stuff into orbit and on interplanetary and interstellar probes is carbon negative (the carbon put into the atmosphere from the combustion during launch was already here).

        With that mindset, it sounds like the only solutions for a carbon negativ

        • by Surt (22457) on Tuesday November 13 2007, @08:03PM (#21343723) Homepage Journal
          I believe the tradition is that carbon neutral means into the air in modern times.

          When you burn fossil fuels, you release carbon into the air that was not fixed into the fuel in modern times. So you release 'new' carbon into the air. Carbon positive.

          When you burn these fuels, you re-release carbon into the air which was fixed in the last year. This is carbon neutral (no change to atmospheric carbon over short time horizon).

          If you take some plants that have fixed some carbon and bury them under a continental fold, that's carbon negative.
        • by GryMor (88799) on Tuesday November 13 2007, @08:34PM (#21344031)
          I wonder what the actual efficiency is if you take into account sequestering the CO2. It should be feasible since you have to sequester the hydrogen anyway and the CO2 is produced in the reactor, that is, fixed infrastructure, rather than in the eventual fuel consuming entity.

          Hell, how much net CO2 could you pull out of the atmosphere with an un fertilized acre of land and a reactor thats producing the hydrogen/electricity needed to fuel the entire endeavor? How does it compare to the real efficiency of current solar cells (after taking into account manufacturing costs/outputs)?
  • by Degrees (220395) <degrees.sbcglobal@net> on Tuesday November 13 2007, @07:10PM (#21343093) Homepage Journal
    In America, researchers apply a jolt of electricity to their wastewater bacteria. In Soviet Russia, the brew tases you! Don't Tase me, brew!
  • by AJWM (19027) on Tuesday November 13 2007, @07:11PM (#21343111) Homepage
    bringing the resulting system up to better than 80 percent efficiency when considering all energy inputs and outputs. (emphasis added)

    So like, dudes, where does that other 20% of the energy go? The Phantom Zone? No, wait, that'd be an energy output too.

    Maybe the system just gets heavier.
  • by Bones3D_mac (324952) on Tuesday November 13 2007, @09:44PM (#21344613)
    Just a thought here, but once this system reached a one-to-one ratio with our current fossil-fuel usage, it may only take a single asshat to engineer and deploy a virus capable of crippling an entire country.

    Somehow, I doubt a city/state/country-wide quarantine on vehicles (and other devices) using such a system would be a trivial task.
    • by Radon360 (951529) on Tuesday November 13 2007, @09:12PM (#21344353)

      Here's one possible solution:

      Bubble it into water in which you release into shallow man-made ponds in order to accelerate algae growth. Harvest the resultant algae, squeeze the oil out of it and make biodiesel. Put the leftovers from that into a fermenter and get what amount of ethanol you can from it. Then dump whatever is leftover from that onto fields to decompose and enrich the soil.

      Yes, you are eventually liberating the carbon again in multiple paths, but it comes down to whether you want to actually sequester the carbon, or are willing to recycle it through a number of diversified fuels as many times as possible.

    • by aktbar (22510) on Tuesday November 13 2007, @09:52PM (#21344699)

      What happens if you repeat the cycle of: {snip}
      an infinite amount of times? You run out of water.

      There are a few reasons to not worry about this:

      (1) The volume of the earths oceans is enough that if we were destroying water in them at the rate at which we burn oil, it would take a few hundred million years to run out. We wouldn't be destroying it at that rate (I would guess, since you can make a lot of hydrogen from just a little water), but even if we were we have a while to figure out a solution.

      (2) Hydrogen and ozone react really well -- the hydrogen wouldn't make it out of the atmosphere before it got bound back up as water.

      The down side of (2) is that we could damage the ozone layer with leaked hydrogen (http://gcep.stanford.edu/research/factsheets/effects_climate.html [stanford.edu])